1158722-63-4

Upstream product

• 95-20-5 2-methyl-1H-indole 
• 105-45-3 acetoacetic acid methyl ester 
• 42924-77-6 (E)-methyl 3-(2-methyl-1H-indol-3-yl)but-2-enoate 
• 98-09-9 benzenesulfonyl chloride 

Downstream Products

• 1269632-15-6 diethyl {3-[1-(methoxycarbonyl)prop-1-en-2-yl]-1-(phenylsulfonyl)-indol-2-yl}methylphosphonate 
• 1269632-16-7 methyl (2E)-3-[2-(2-nitrostyryl)-1-(phenylsulfonyl)indol-3-yl]but-2-enoate 
• 1269632-25-8 methyl (2E)-3-[2-(4',5'-dimethoxy-2-nitrostyryl)-1-(phenylsulfonyl)indol-3-yl]but-2-enoate 
• 1269632-26-9 methyl (2E)-3-[2-(4'-chloro-2'-nitrostyryl)-1-(phenylsulfonyl)indol-3-yl]but-2-enoate 
• 1269632-27-0 methyl (2E)-3-[2-(4'-fluoro-2'-nitrostyryl)-1-(phenylsulfonyl)indol-3-yl]but-2-enoate 
• 1269632-28-1 (2E)-methyl 3-(2-(5-fluoro-2-nitrostyryl)-1-phenylsulfonylindol-3-yl)but-2-enoate 
• 1269632-29-2 methyl (2E)-3-[2-(4',5'-methylenedioxy-2'-nitrostyryl)-1-(phenylsulfonyl)indol-3-yl]but-2-enoate 
• 1269632-54-3 (2E)-methyl 3-(2-(2-azidostyryl)-1-phenylsulfonylindol-3-yl)-3-methylacrylate 
• 1269632-14-5 methyl 3-[2-bromomethyl-1-(phenylsulfonyl)indol-3-yl]but-2-enoate 

Relevant academic research and scientific papers

Synthetic studies on indolocarbazoles: A facile synthesis of staurosporinone analogues

Synthesis of indolocarbazoles was achieved through thermal electrocyclization followed by triethyl phosphite-mediated nitrene insertion reactions. Total synthesis of staurosporinone analogues was achieved from commercially available 2-methylindole. The CD

Synthetic studies on indolocarbazoles: Total synthesis of staurosporine aglycon

A synthesis of staurosporine aglycon and its analogs was achieved in a 28-36% overall yield starting from 2-methylindole. The prominent key steps for the synthesis of the indolocarbazole alkaloids involved electrocyclization and nitrene insertion reactions.

Synthesis of substituted carbazoles via electrocyclization of in situ generated enamines from 1-phenylsulfonyl-2/(3)-methyl-3/(2)-vinylindoles and DMF·DMA/DMA·DMA

Interaction of 2/(3)-methyl-3/(2)-vinylindoles and DMF·DMA/DMA·DMA at 110 °C led to the in situ generation of enamines, which on concurrent electrocyclization followed by subsequent aromatization afforded substituted carbazoles.