115878-99-4

Basic information

• Product Name: (R)-1-<(4-methylphenyl)sulphinyl>-4-methyl-3-pentene
• CAS NO: 115878-99-4
• Molecular Weight: 222.351
• Mol File: 115878-99-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-1-<(4-methylphenyl)sulphinyl>-4-methyl-3-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-<(4-methylphenyl)sulphinyl>-4-methyl-3-pentene(115878-99-4)
• EPA Substance Registry System: (R)-1-<(4-methylphenyl)sulphinyl>-4-methyl-3-pentene(115878-99-4)

Safety Data

• Hazardous Substances Data: 115878-99-4(Hazardous Substances Data)

Upstream product

• 453-18-9 methyl fluoroacetate 
• 118558-73-9 (+)-(R_S)-5-<(4-Methylphenyl)sulfinyl>pent-1-ene 

Downstream Products

• 220272-58-2 (3R/S)-1,1,1-trifluoro-3-<(R)-(4-methylphenyl)sulphinyl>-6-methyl-5-hepten-2-one 
• 220272-54-8 (3RS,R_S)-1-fluoro-6-methyl-3-<(4-methylphenyl)sulphinyl>-5-hepten-2-one 
• 126924-76-3 (2R,3R)-1,1,1-trifluoro-3-<(R)-(4-methylphenyl)sulphinyl>-6-methyl-5-hepten-2-ol 
• 126887-70-5 (2R,3S)-1,1,1-trifluoro-3-<(R)-(4-methylphenyl)sulphinyl>-6-methyl-5-hepten-2-ol 
• 126924-75-2 (2S,3S)-1,1,1-trifluoro-3-<(R)-(4-methylphenyl)sulphinyl>-6-methyl-5-hepten-2-ol 
• 126887-74-9 (2R,3R)-1,1,1-trifluoro-3-<(4-methylphenyl)sulphenyl>-6-methyl-5-hepten-2-ol 
• 126887-72-7 (2R,3S)-1,1,1-trifluoro-3-<(4-methylphenyl)sulphenyl>-6-methyl-5-hepten-2-ol 
• 246028-15-9 (2R,R_S)-diethyl 1,1-difluoro-2-hydroxy-6-methyl-3-(4-methylphenylsulfinyl)-hept-5-enylphosphonate 
• 246028-17-1 (2S,R_S)-diethyl 1,1-difluoro-2-hydroxy-6-methyl-3-(4-methylphenylsulfinyl)-hept-5-enylphosphonate 

Relevant articles and documents

NEW CHIRONS FOR THE SYNTHESIS OF FLUORINE-CONTAINING COMPOUNDS. AN EFFICIENT ENTRANCE TO α-MONO- AND POLY-FLUORO KETONES HAVING A CHIRAL α'-SULPHINYL SUBSTITUENT

The lithium derivatives of optically pure alkyl p-tolyl sulphoxides, having both the R and S absolute configurations at the sulphur atom, have been condensed with the esters of mono- and poly-fluorocarboxylic acids to give several mono- and poly-fluoro ketones with a chiral sulphinyl substituent.The compounds having an alkyl residue on the α or α' position of the ketone group have also been obtained through alkylation of the di-, or mono-anion of the unsubstituted terms.Products chiral only at the sulphur atom, at the sulphur and the fluorinated carbon atom, or at the sulphur and the sulphinyl-substituted carbon have been obtained as single pure enantiomers.