115890-32-9Relevant articles and documents
Enantioselective synthesis of (-)-kainic acid
Takano,Sugihara,Satoh,Ogasawara
, p. 6467 - 6471 (1988)
Novel diastereoselectivity in the intramolecular Diels-Alder reaction of the heterodiene 18 has been observed. The structure of the cycloadduct was determined to be 20, possessing cis-5/6 ring juncture by converting it into (-)-kainic acid and kainic acid lactone.
Synthesis of the 1,4-diazepan-2-one moiety of liposidomycins
Kim, Kwan Soo,Cho, In Haeng,Ahn, Yeong Hee,Park, Jong Ii
, p. 1783 - 1786 (2007/10/02)
The two stereoisomers 12 and 16 of 1,4-dimethyl-1,4-diazepan-2-one, a central feature of liposidomycins, have been synthesized starting from L-ascorbic acid and sarcosine.