Enantioselective synthesis of (-)-kainic acid

DOI: 10.1021/ja00227a029

Source and publish data:

Journal of the American Chemical Society p. 6467 - 6471 (1988)

Update date:2022-09-26

Topics:

Authors:

Takano Takano

Sugihara

Satoh Satoh

Ogasawara

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Article abstract of DOI:10.1021/ja00227a029

Novel diastereoselectivity in the intramolecular Diels-Alder reaction of the heterodiene 18 has been observed. The structure of the cycloadduct was determined to be 20, possessing cis-5/6 ring juncture by converting it into (-)-kainic acid and kainic acid lactone.

Full text of DOI:10.1021/ja00227a029

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