
Journal of the American Chemical Society p. 6467 - 6471 (1988)
Update date:2022-09-26
Topics:
Takano
Sugihara
Satoh
Ogasawara
Novel diastereoselectivity in the intramolecular Diels-Alder reaction of the heterodiene 18 has been observed. The structure of the cycloadduct was determined to be 20, possessing cis-5/6 ring juncture by converting it into (-)-kainic acid and kainic acid lactone.
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