1159268-04-8

Basic information

• Product Name: (S)-dimethyl 2-(1-(2-chlorophenyl)-2-nitroethyl)-2-fluoromalonate
• Synonyms: (S)-dimethyl 2-(1-(2-chlorophenyl)-2-nitroethyl)-2-fluoromalonate
• CAS NO: 1159268-04-8
• Molecular Weight: 333.701
• Mol File: 1159268-04-8.mol

Chemical Properties

• CAS DataBase Reference: (S)-dimethyl 2-(1-(2-chlorophenyl)-2-nitroethyl)-2-fluoromalonate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-dimethyl 2-(1-(2-chlorophenyl)-2-nitroethyl)-2-fluoromalonate(1159268-04-8)
• EPA Substance Registry System: (S)-dimethyl 2-(1-(2-chlorophenyl)-2-nitroethyl)-2-fluoromalonate(1159268-04-8)

Safety Data

• Hazardous Substances Data: 1159268-04-8(Hazardous Substances Data)

Upstream product

• 344-14-9 dimethyl 2-fluoromalonate 
• 22568-07-6 1-chloro-2-[(E)-2-nitrovinyl]benzene 

Relevant articles and documents

Organocatalytic enantioselective conjugate addition of 2-fluoromalonate to nitroolefins: Direct synthesis of chiral fluorinated γ-nitro carboxylic acid derivatives

An unprecedented organocatalytic asymmetric Michael addition of fluorine-containing carbon-centered nucleophiles to nitroolefins has been described. The process features the creation of a fluorine-containing quaternary carbon center and an adjacent chiral

Organocatalytic asymmetric synthesis of chiral fluorinated quaternary carbon containing β-ketoesters

Organocatalytic enantioselective conjugate addition of α- fluoroketoesters to nitroolefins efficiently catalyzed by a cinchona alkaloid-derivative affords versatile non-enolizable ketoesters by forming two consecutive fluorinated quaternary and tertiary c