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1160184-14-4

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1160184-14-4 Usage

General Description

2,6-Dibromo-4-iodopyridine is a reactive organic compound that falls under the category of organobromides. It contains both bromine and iodine substituents on a pyridine ring, a basic six-membered ring with one nitrogen atom. 2,6-DibroMo-4-iodopyridine is known for its use in various syntheses and applications in the field of organic chemistry, where it often acts as a building block. The presence of halogens like bromine and iodine allows it to react easily with other compounds, making it quite versatile. However, due to the reactivity of these halogens, certain precautions should be taken while handling 2,6-Dibromo-4-iodopyridine. As with many chemical substances, it requires proper storage and disposal systems.

Check Digit Verification of cas no

The CAS Registry Mumber 1160184-14-4 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,6,0,1,8 and 4 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1160184-14:
(9*1)+(8*1)+(7*6)+(6*0)+(5*1)+(4*8)+(3*4)+(2*1)+(1*4)=114
114 % 10 = 4
So 1160184-14-4 is a valid CAS Registry Number.

1160184-14-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,6-Dibromo-4-iodopyridine

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1160184-14-4 SDS

1160184-14-4Upstream product

1160184-14-4Relevant articles and documents

Excitation Energy-Dependent Branching Dynamics Determines Photostability of Iron(II)-Mesoionic Carbene Complexes

Nair, Shruthi S.,Bysewski, Oliver A.,Kupfer, Stephan,W?chtler, Maria,Winter, Andreas,Schubert, Ulrich S.,Dietzek, Benjamin

, p. 9157 - 9173 (2021)

Photoactive metal complexes containing earth-abundant transition metals recently gained interest as photosensitizers in light-driven chemistry. In contrast to the traditionally employed ruthenium or iridium complexes, iron complexes developed to be promising candidates despite the fact that using iron complexes as photosensitizers poses an inherent challenge associated with the low-lying metal-centered states, which are responsible for ultrafast deactivation of the charge-transfer states. Nonetheless, recent developments of strongly σ-donating carbene ligands yielded highly promising systems, in which destabilized metal-centered states resulted in prolonged lifetimes of charge-transfer excited states. In this context, we introduce a series of novel homoleptic Fe-triazolylidene mesoionic carbene complexes. The excited-state properties of the complexes were investigated by time-resolved femtosecond transient absorption spectroscopy and quantum chemical calculations. Pump wavelength-dependent transient absorption reveals the presence of distinct excited-state relaxation pathways. We relate the excitation-wavelength-dependent branching of the excited-state dynamics into various reaction channels to solvent-dependent photodissociation following the population of dissociative metal centered states upon excitation at 400 nm.

Deprotonative metalation of chloro- and bromopyridines using amido-based bimetallic species and regioselectivity-computed CH acidity relationships

Snegaroff, Katia,Nguyen, Tan Tai,Marquise, Nada,Halauko, Yury S.,Harford, Philip J.,Roisnel, Thierry,Matulis, Vadim E.,Ivashkevich, Oleg A.,Chevallier, Floris,Wheatley, Andrew E. H.,Gros, Philippe C.,Mongin, Florence

experimental part, p. 13284 - 13297 (2012/02/03)

A series of chloro- and bromopyridines have been deprotometalated by using a range of 2,2,6,6-tetramethylpiperidino-based mixed lithium-metal combinations. Whereas lithium-zinc and lithium-cadmium bases afforded different mono- and diiodides after subsequent interception with iodine, complete regioselectivities were observed with the corresponding lithium-copper combination, as demonstrated by subsequent trapping with benzoyl chlorides. The obtained selectivities have been discussed in light of the CH acidities of the substrates, determined both in the gas phase and as a solution in THF by using the DFT B3LYP method.

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