116052-71-2

Basic information

• Product Name: silver dicyclohexylphosphinate
• CAS NO: 116052-71-2
• Molecular Weight: 337.147
• Mol File: 116052-71-2.mol

Chemical Properties

• CAS DataBase Reference: silver dicyclohexylphosphinate(CAS DataBase Reference)
• NIST Chemistry Reference: silver dicyclohexylphosphinate(116052-71-2)
• EPA Substance Registry System: silver dicyclohexylphosphinate(116052-71-2)

Safety Data

• Hazardous Substances Data: 116052-71-2(Hazardous Substances Data)

Upstream product

• 832-39-3 dicyclohexylphosphinic acid 

Downstream Products

• 116076-45-0 dimeric n-butyloxotin bis(dicyclohexylphosphinate) 
• 116076-48-3 {((C₄H₉)Sn(OH)O₂P(C₆H₁₁)2)3O}⁽¹⁺⁾*{(C₆H₁₁)2PO₂}^(1-)={((C₄H₉)Sn(OH)O₂P(C₆H₁₁)2)3O}{(C₆H₁₁)2PO₂} 

Relevant articles and documents

Dinuclear and tetranuclear cages of oxodiphenylantimony phosphinates: Synthesis and structures

The novel dimeric compounds [Ph2Sb(O2PR2)O]2·2CH 2Cl2 [R - cycl-C6H11 (2) and cycl-C8H15 (3)] have been synthesized by reacting diphenylantimony

Diphenylantimony(V) Oxo/Chloro Carboxylates and Phosphinates: Crystal Structures of >2O and 2O

Reaction of SbPh2Cl3 (1 mol) with the silver salt of dicyclohexylphosphinic acid (2 mol) afforded >2O 1; a similar reaction with AgO2P(C8H15)2 gave a product formulated as >2O.Similar reactions with silver carboxylates (1:3 stoichiometry) led to the crystalline derivatives 2O (R = Ph 3, CHPh2 4, 2,4,6-Me3C6H2 5, 2-MeC6H4 6 or 4-MeC6H4 7), whereas the 1:2 reaction afforded crystalline SbPh2Cl(O2CR)2 (R = Ph 8, 2-MeC6H4 9 or 4-MeC6H4 10).Interconversion of the previously known compounds O and Sb4Ph8O6*3MeCO2H was achieved and established by 1H NMR spectroscopy.Compounds 1 and 3 were further characterized by X-ray diffraction; the antimony in 1 is six-co-ordinated with bridging phosphinates whereas in 3 is seven-co-ordinated with chelating benzoates.Short Sb-O (oxo) distances (1.923 Angstroem) and near linearity at the bridging oxygen (Sb-O-Sb 173.9 deg) are observed for 3.