1160525-56-3

Basic information

• Product Name: C₅₉H₅₂O₁₁
• Synonyms: C₅₉H₅₂O₁₁
• CAS NO: 1160525-56-3
• Molecular Weight: 937.055
• Mol File: 1160525-56-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₅₉H₅₂O₁₁(CAS DataBase Reference)
• NIST Chemistry Reference: C₅₉H₅₂O₁₁(1160525-56-3)
• EPA Substance Registry System: C₅₉H₅₂O₁₁(1160525-56-3)

Safety Data

• Hazardous Substances Data: 1160525-56-3(Hazardous Substances Data)

Upstream product

• 13036-02-7 Dimethyl 5-hydroxyisophthalate 
• 129536-40-9 [3,5-Bis-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-methanol 
• 129536-41-0 3,5-bis[3,5-bis(benzyloxy)benzyloxy]benzyl bromide 

Relevant articles and documents

Facile synthesis of chiral diphosphine-containing multiple dendrimeric catalysts for enantioselective hydrogenation

A new kind of chiral diphosphine PyrPhos-functionalized codendrimers have been synthesized via a liquid-phase strategy in high yields. The resulting dendrimeric PyrPhos ligands were purified by a simple solvent precipitation without the need for chromatographic separation, and well characterized by 1H, 13C and 31P NMR, MALDI-TOF mass spectroscopy as well as elemental analysis. Their rhodium complexes were applied to the asymmetric hydrogenation of α-acetamido cinnamic acids. Excellent enantioselectivities were achieved, which are comparable to those with the corresponding small molecular catalysts. In addition, these codendrimeric catalysts showed better catalytic performance than the dendrimeric catalysts with Rh(PyrPhos) sites located in the focal point of poly(aryl ether) dendrons or in the periphery of poly(propyleneimine) dendrimers.

Supramolecular chiral dendritic monophosphites assembled by hydrogen bonding and their use in the Rh-catalyzed asymmetric hydrogenation

A new type of supramolecular chiral dendritic monophosphite ligands has been prepared via a hydrogen-bonding assembly. The Rh complexes of these supramolecular ligands have been successfully applied in the asymmetric hydrogenation of enamides and dehydroa