116053-72-6

Basic information

• Product Name: (E)-Hexa-1,4-dien-3-yl-hydroperoxide
• Synonyms: (E)-Hexa-1,4-dien-3-yl-hydroperoxide
• CAS NO: 116053-72-6
• Molecular Weight: 114.144
• Mol File: 116053-72-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-Hexa-1,4-dien-3-yl-hydroperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-Hexa-1,4-dien-3-yl-hydroperoxide(116053-72-6)
• EPA Substance Registry System: (E)-Hexa-1,4-dien-3-yl-hydroperoxide(116053-72-6)

Safety Data

• Hazardous Substances Data: 116053-72-6(Hazardous Substances Data)

Upstream product

• 6108-61-8 cis,cis-2,4-Hexadien 
• 5194-50-3 (E,Z)-2,4-hexadiene 
• 5194-51-4 (2E,4E)-hexa-2,4-diene 

Relevant articles and documents

Chemistry of Singlet Oxygen. 51. Zwitterionic Intermediates from 2,4-Hexadienes

The three isomeric 2,4-hexadienes give nearly identical product distributions with singlet oxygen.Singlet oxygen causes rapid interconversion of the isomers, and methoxy hydroperoxides are formed from all three dienes in methanol (E,Z and Z,Z ca. 25 percent, E,E 10 percent).These observations are explained by intermediate zwitterions that revert to isomerized dienes in competition with collapse to products or capture by methanol.