116059-35-9Relevant academic research and scientific papers
Oxidation of sulfonyl carbanions with lithium t-butyl peroxide: formation of β-hydroxy-sulfones
Chemla, Fabrice,Julia, Marc,Uguen, Daniel
, p. 639 - 641 (2007/10/02)
Lithiated primary sulfones were converted into high yields of symmetrical β-hydroxy-sulfones by lithium tert-butyl peroxide (LTBP). - Keywords: oxidation / sulfonylcarbanion / lithium tert-butyl peroxide / β-hydroxy-sulfones
Syntheses with Sulfones L : Preparation of β-Hydroxysulfones through the Combined Oxidative Desulfonylation/Condensation Reaction of Sulfonyl Anions. Application to Terpene Synthesis.
Capet, M.,Cuvigny, T.,Penhoat, C. Herve du,Julia, M.,Loomis, G.
, p. 6273 - 6276 (2007/10/02)
The oxidative desulfonylation of primary sulfonyl anions with the molybdenum peroxide reagent, MoO5.Py.HMPA, leads directly to β-hydroxysulfones through condensation of the starting α-sulfonyl anion with the aldehyde formed in situ.Symmetrical polyenes such as (Z)-12-dehydrosqualene and (Z)-16-phytoene have been obtained in three steps in > 87percent stereoslectivity from the corresponding β-hydroxysulfones.
