1160612-01-0

Basic information

• Product Name: [(HC(CMeN-2,6-(i-Pr)2C₆H₃)2)Ge(OC₆F₅)]
• CAS NO: 1160612-01-0
• Molecular Weight: 673.305
• Mol File: 1160612-01-0.mol

Chemical Properties

• CAS DataBase Reference: [(HC(CMeN-2,6-(i-Pr)2C₆H₃)2)Ge(OC₆F₅)](CAS DataBase Reference)
• NIST Chemistry Reference: [(HC(CMeN-2,6-(i-Pr)2C₆H₃)2)Ge(OC₆F₅)](1160612-01-0)
• EPA Substance Registry System: [(HC(CMeN-2,6-(i-Pr)2C₆H₃)2)Ge(OC₆F₅)](1160612-01-0)

Safety Data

• Hazardous Substances Data: 1160612-01-0(Hazardous Substances Data)

Upstream product

• 908373-69-3 [((2,6-(i-Pr)2C₆H₃)NC(=CH₂)CH=C(Me)N(2,6-(i-Pr)2C₆H₃))Ge] 
• 771-61-9 2,3,4,5,6-pentafluorophenol 

Relevant articles and documents

Stable compounds of composition LGe(II)R (R = OH, PhO, C6F 5O, PhCO2) prepared by nucleophilic addition reactions

The stable β-diketiminate germanium(II) compounds LGeR [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3] (R = OTf, OH, PhO, C6F5O, PhCO2) are described. LGeOTf (2) is synthesized by salt metathesis reaction of LGeCl (1) with AgOTf and can be isolated as colorless crystals in 90% yield. Compound L'Ge (3) (L' = CH{(C=CH2)(CMe)(2,6-iPr2C6H3N) 2}) was obtained by treatment of LGeOTf (2) with 1 equiv of 1,3di-tert-butylimidazol-2-ylidene (NHC) in toluene. Reaction of 3 with H 2O, PhOH, C6F5OH, and PhCO2H, respectively, in toluene provided the germanium(II) compounds 4-7 in high yield. Compounds 2-7 were characterized by microanalysis and multinuclear NMR spectroscopy. Furthermore compounds 5, 6, and 7 are confirmed by X-ray structural analysis with the result that compounds 5,6, and 7 are monomeric and the germanium center resides in a trigonal-pyramidal environment.