908373-69-3

Basic information

• Product Name: [((2,6-(i-Pr)2C₆H₃)NC(=CH₂)CH=C(Me)N(2,6-(i-Pr)2C₆H₃))Ge]
• Synonyms: [((2,6-(i-Pr)2C₆H₃)NC(=CH₂)CH=C(Me)N(2,6-(i-Pr)2C₆H₃))Ge]
• CAS NO: 908373-69-3
• Molecular Weight: 489.24
• Mol File: 908373-69-3.mol

Chemical Properties

• CAS DataBase Reference: [((2,6-(i-Pr)2C₆H₃)NC(=CH₂)CH=C(Me)N(2,6-(i-Pr)2C₆H₃))Ge](CAS DataBase Reference)
• NIST Chemistry Reference: [((2,6-(i-Pr)2C₆H₃)NC(=CH₂)CH=C(Me)N(2,6-(i-Pr)2C₆H₃))Ge](908373-69-3)
• EPA Substance Registry System: [((2,6-(i-Pr)2C₆H₃)NC(=CH₂)CH=C(Me)N(2,6-(i-Pr)2C₆H₃))Ge](908373-69-3)

Safety Data

• Hazardous Substances Data: 908373-69-3(Hazardous Substances Data)

Upstream product

• 382150-90-5 (HC(CMeNC-2,6-i-Pr₂C₆H₃)2)-germanium(II) hydride 
• 373383-58-5 [C₃H(CH₃)2(N(C₆H₃(C₃H₇)2))2Ge]⁽¹⁺⁾ 
• 334719-93-6 [C₃H(CH₃)2(N(2,6-diisopropylphenyl))2 chlorogermylene] 
• 1040234-97-6 [(HC(CMeN-2,6-(i-Pr)2C₆H₃)2)GeOTf] 

Downstream Products

• 908373-71-7 bis[C₃H(CH₃)(CH₂)(N(2,6-diisopropylphenyl))2 bromogermylene] 
• 1093122-51-0 CHC(CH₂)C(CH₃)(NC₆H₃(C₃H₇)2)2Ge(HCCH) 
• 1093122-52-1 CHC(CH₂)C(CH₃)(NC₆H₃(C₃H₇)2)2Ge(HCCC₆H₅) 
• 1107656-04-1 (H₂N)GeN(C₆H₃(CH(CH₃)2)2)C(CH₃)CHC(CH₃)NC₆H₃(CH(CH₃)2)2 
• 382150-90-5 (HC(CMeNC-2,6-i-Pr₂C₆H₃)2)-germanium(II) hydride 
• 692776-46-8 (N(2,6-i-Pr₂C₆H₃)C(Me)CHC(Me)N(2,6-i-Pr₂C₆H₃))GeOH 
• 1160612-00-9 [(HC(CMeN-2,6-(i-Pr)2C₆H₃)2)Ge(OPh)] 
• 1160612-02-1 [(HC(CMeN-2,6-(i-Pr)2C₆H₃)2)Ge(O₂CPh)] 
• 1160612-01-0 [(HC(CMeN-2,6-(i-Pr)2C₆H₃)2)Ge(OC₆F₅)] 
• 1177424-84-8 [B(C₆F₅)3(CH(CCH₂)(CMe)(N(2,6-(i-Pr)2C₆H₃))2)Ge] 
• 1201180-14-4 (2,6-iPr₂C₆H₃)2(C₃HN₂Ge)(O)CH₃(CH₂)(1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) 
• 1314090-41-9 (CH₂)(CH₃)C₃HN₂(C₆H₃(C₃H₇)2)2Ge(C₆H₅)(C₄H₉)2CN₂GeCl 
• 1236133-37-1 (CH(CMe)2[N(2,6-(i)Pr₂C₆H₃)]2)GeN(C₆F₅)2 

Relevant articles and documents

Dehydrogenation of LGeH by a lewis N-heterocyclic carbene borane pair under the formation of L'Ge and its reactions with B(C6F5) 3 and trimethylsilyl diazomethane: An unprecedented rearrangement of a diazocompound to an is

Herein we report the dehydrogenation of LGeH (1) [L = CH{(CMe)(2,6-/Pr 2C6H3N)}2] by a frustrated Lewis NHC borane pair under the formation of an imidazolium borate salt (2) and the heterocyclic germylene L'Ge (

Stable compounds of composition LGe(II)R (R = OH, PhO, C6F 5O, PhCO2) prepared by nucleophilic addition reactions

The stable β-diketiminate germanium(II) compounds LGeR [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3] (R = OTf, OH, PhO, C6F5O, PhCO2) are described. LGeOTf (2) is synthesized by salt metathesis reaction of LGeCl (1) with AgOTf and can be isolated as colorless crystals in 90% yield. Compound L'Ge (3) (L' = CH{(C=CH2)(CMe)(2,6-iPr2C6H3N) 2}) was obtained by treatment of LGeOTf (2) with 1 equiv of 1,3di-tert-butylimidazol-2-ylidene (NHC) in toluene. Reaction of 3 with H 2O, PhOH, C6F5OH, and PhCO2H, respectively, in toluene provided the germanium(II) compounds 4-7 in high yield. Compounds 2-7 were characterized by microanalysis and multinuclear NMR spectroscopy. Furthermore compounds 5, 6, and 7 are confirmed by X-ray structural analysis with the result that compounds 5,6, and 7 are monomeric and the germanium center resides in a trigonal-pyramidal environment.

Cleavage of a N-H bond of ammonia at room temperature by a germylene

The reaction of LGeCI [1; L = CH{(CMe)(2,6-iPr2C 6H3N)}2] with 1,3-di-tert-butylimidazol-2- ylidene results in the formation of the germylene L′Ge [2; L′ = CH{(C=CH2)(CMe)(2,6-iP

A heterofulvene-like germylene with a betain reactivity

An electronic chameleon: The planar cyclogermylene 1 can be described by the resonance structures 1A and 1B. It is accessible in 79% yield by dehydrohalogenation of the corresponding (β-diketiminato)chlorogermylene by LiN(SiMe3)2. Al