1161-08-6 Usage
Uses
Used in Chemiluminescence Applications:
Bis(2,4-dichlorophenyl)oxalate is utilized as a sensitizer in chemiluminescence reactions for its ability to produce light. This characteristic makes it a valuable component in various applications that require light emission without the need for external energy sources.
Used in Glow Sticks Production:
In the entertainment and safety industries, Bis(2,4-dichlorophenyl)oxalate is used as a key component in the production of glow sticks. Its role in these light-emitting products ensures a safe, portable, and temporary source of illumination for various purposes, including recreational activities, emergency situations, and decorative lighting.
Used in Light-Emitting Products:
Beyond glow sticks, Bis(2,4-dichlorophenyl)oxalate is also employed in the development of other light-emitting products. Its chemiluminescent properties allow for the creation of innovative devices and tools that capitalize on its ability to generate light through chemical reactions, offering a range of possibilities across different sectors.
Check Digit Verification of cas no
The CAS Registry Mumber 1161-08-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,6 and 1 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1161-08:
(6*1)+(5*1)+(4*6)+(3*1)+(2*0)+(1*8)=46
46 % 10 = 6
So 1161-08-6 is a valid CAS Registry Number.
InChI:InChI=1/C14H6Cl4O4/c15-7-1-3-11(9(17)5-7)21-13(19)14(20)22-12-4-2-8(16)6-10(12)18/h1-6H
1161-08-6Relevant academic research and scientific papers
The Hammett correlation between distyrylbenzene substituents and chemiluminescence efficiency providing various ρ-values for peroxyoxalate chemiluminescence of several oxalates
Maruyama, Takayuki,Narita, Susumu,Motoyoshiya, Jiro
, p. 222 - 231 (2013/03/13)
Peroxyoxalate chemiluminescence (PO-CL) was investigated using eight oxalates with various phenol moieties and the distyrylbenzene (DSB) fluorophores with various substituents. The ρ-values in the Hammett correlation between the substituent constants (σp+) of the DSBs and the singlet chemiexcitation yields (ΦS) for the PO-CL reactions varied from -0.50 to -1.01 depending on the oxalate structure, and the reactive oxalates tended to afford the higher absolute ρ-values but with a few exceptions. Based on the CIEEL mechanism, these experimental observations suggest that the aryloxy groups still remain in the 1,2-dioxetanones (DOTs), which are the postulated high-energy intermediates, and control the electronic properties of DOTs as electron-acceptors. The LUMO energies of the DOTs calculated by the ab initio method with a B3LYP/6-31g(d) basis set reveal that the lower the DOT-LUMO energies, the higher the absolute ρ-values were provided for the corresponding oxalates, as predicted by the frontier molecular orbital (FMO) theory. Thus, the chemical species interacting with the DSBs would be not unitary and will be DOTs.
