116103-02-7

Upstream product

• 122350-80-5 1,5-anhydro-2-deoxy-6-O-trityl-D-arabino-hex-1-enitol 
• 129870-14-0 3,4-di-O-benzyl-6-O-trityl-D-glucal 
• 116102-90-0 tert-butyldimethylsilyl 2-azido-3,4-di-O-benzyl-2-deoxy-6-O-trifluoromethanesulfonyl-β-D-glucopyranoside 
• 129870-15-1 tert-butyldimethylsilyl 2-azido-3,4-di-O-benzyl-2-deoxy-6-O-trityl-β-D-glucopyranoside 
• 116103-00-5 tert-butyldimethylsilyl 2-azido-3,4-di-O-benzyl-2-deoxy-6-O-(4,5:7,8-di-O-cyclohexylidene-3-deoxy-α-D-manno-2-octulopyranosylonate)-β-D-glucopyranoside 
• 116102-91-1 tert-butyldimethylsilyl 2-azido-3,4-di-O-benzyl-2-deoxy-6-O-(4,5:7,8-di-O-cyclohexylidene-3-deoxy-N-methyl-α-D-manno-2-octulopyranosylonamide)-β-D-glucopyranoside 
• 13265-84-4 D-glucal 
• 100-39-0 benzyl bromide 
• 129891-66-3 2-azido-2-deoxy-3,4-O-dibenzyl-1-O-tert-butyldimethylsilyl-β-D-glucopyranoside 
• 116103-01-6 C₄₇H₆₉NO₁₂Si 
• 112-64-1 tetradecanoyl chloride 

Downstream Products

• 129891-71-0 1-O-acetyl-3,4-di-O-benzyl-2-deoxy-6-O-(methyl 4,5,7,8-tetra-O-acetyl-3-deoxy-α-D-manno-2-octulopyranosylonate)-2-tetradecanoylamino-α-D-glucopyranose 

Relevant academic research and scientific papers

O-Alkylation at the anomeric centre for the stereoselective synthesis of Kdo-α-glycosides

O-Alkylation at the anomeric centre of the dianion of 4,5:7,8-di-O-cyclohexylidene-3-deoxy-N-methyl-α-D-manno-octulopyranosonamide (1) with several triflates led diastereoselectively to the α-glycosides.In this way, lipopolysaccharide building-blocks cont