116203-82-8Relevant academic research and scientific papers
ONE-POT OXIDATION AND NITROSATION OF β-ALKANOLAMINES WITH KMnO4-NaNO2. A CONVENIENT PREPARATION OF β-KETONITROSAMINES
Pei, Guo-Kui,Farnsworth, David W.,Saavedra, Joseph E.
, p. 207 - 214 (2007/10/02)
The oxidation and nitrosation of β-alkanolamines to the corresponding β-ketonitrosamines is reported.The oxidation is carried out with potassium permanganate in acidic medium, followed by nitrosation of the protonated aminoketone, with sodium nitrite, to the corresponding β-ketonitrosamine.
OXIDATION OF β-HYDROXYNITROSAMINES AND β-HYDROXYNITROSOUREAS TO THE CORRESPONDING β-OXO DERIVATIVES WITH CrO3/CELITE OR CrO3/FLORISIL IN NON-AQUEOUS MEDIA
Saavedra, Joseph E.,Farnsworth, David W.,Pei, Guo-Kui
, p. 313 - 322 (2007/10/02)
The oxidation of β-hydroxynitrosamines and β-hydroxynitrosoureas in ethyl acetate with chromic anhydride suspended in Celite or Florisil is reported.The reaction proceeded within 5-25 min, the yields were generally high, and the work-up procedure simple.T
