116270-20-3

Basic information

• Product Name: E-ethyl 3-azidoacrylate
• Synonyms: E-ethyl 3-azidoacrylate
• CAS NO: 116270-20-3
• Molecular Weight: 141.129
• Mol File: 116270-20-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: E-ethyl 3-azidoacrylate(CAS DataBase Reference)
• NIST Chemistry Reference: E-ethyl 3-azidoacrylate(116270-20-3)
• EPA Substance Registry System: E-ethyl 3-azidoacrylate(116270-20-3)

Safety Data

• Hazardous Substances Data: 116270-20-3(Hazardous Substances Data)

Upstream product

• 623-47-2 propynoic acid ethyl ester 

Downstream Products

• 152975-95-6 4-(Ethoxycarbonyl)-1,1-diphenyl-1-methyl-2-aza-1λ⁵-phosphabuta-1,3-diene 

Relevant articles and documents

Organic Azides. 5. A Simple Synthesis of Alkyl 3-Azido-2-alkenoates

The title compounds are derived from alkyl 2-alkynoates and aqueous sodium azide solution under ultrasonic irradiation.At low reaction temperatures the Z-configuration is favoured.Ultrasonic irradiation is decisive for good conversion and in most cases no additional stirring is necessary.Stirring without ultrasonic irradiation gives low conversion.The reaction conditions show high selectivity between nucleophilic addition and nucleophilic substitution.