116278-44-5

Basic information

• Product Name: (2R,3S,4R,5R,6S)-5-Azido-6-[(2S,3R)-2,3-bis-benzyloxy-3-((2R,3S,4S,5S)-3,4,5-tris-benzyloxy-tetrahydro-furan-2-yl)-propoxy]-2-hydroxymethyl-tetrahydro-pyran-3,4-diol
• CAS NO: 116278-44-5
• Molecular Weight: 847.962
• Mol File: 116278-44-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S,4R,5R,6S)-5-Azido-6-[(2S,3R)-2,3-bis-benzyloxy-3-((2R,3S,4S,5S)-3,4,5-tris-benzyloxy-tetrahydro-furan-2-yl)-propoxy]-2-hydroxymethyl-tetrahydro-pyran-3,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4R,5R,6S)-5-Azido-6-[(2S,3R)-2,3-bis-benzyloxy-3-((2R,3S,4S,5S)-3,4,5-tris-benzyloxy-tetrahydro-furan-2-yl)-propoxy]-2-hydroxymethyl-tetrahydro-pyran-3,4-diol(116278-44-5)
• EPA Substance Registry System: (2R,3S,4R,5R,6S)-5-Azido-6-[(2S,3R)-2,3-bis-benzyloxy-3-((2R,3S,4S,5S)-3,4,5-tris-benzyloxy-tetrahydro-furan-2-yl)-propoxy]-2-hydroxymethyl-tetrahydro-pyran-3,4-diol(116278-44-5)

Safety Data

• Hazardous Substances Data: 116278-44-5(Hazardous Substances Data)

Upstream product

• 105592-31-2 benzyl 5,6,7-tri-O-acetyl-2,3-O-isopropylidene-β-L-glycero-D-manno-heptofuranoside 
• 116265-19-1 Benzyl-2,3,5,6-tetra-O-benzyl-7-O-(tert-butyldiphenylsilyl)-L-glycero-α-D-manno-heptofuranosid 
• 116265-17-9 Benzyl-7-O-(tert-butyldiphenylsilyl)-L-glycero-α-D-manno-heptofuranosid 
• 116265-15-7 Benzyl-5,6,7-tri-O-acetyl-L-glycero-α-D-manno-heptofuranosid 
• 116265-16-8 (1R,2S)-1-((2R,3R,4S,5S)-5-Benzyloxy-3,4-dihydroxy-tetrahydro-furan-2-yl)-propane-1,2,3-triol 
• 116265-20-4 Benzyl-2,3,5,6-tetra-O-benzyl-L-glycero-α-D-manno-heptofuranosid 
• 100-39-0 benzyl bromide 
• 67817-15-6 Acetic acid (2R,3S,4R,5R,6R)-4-acetoxy-2-acetoxymethyl-5-azido-6-bromo-tetrahydro-pyran-3-yl ester 
• 56883-33-1 2-azido-2-deoxy-3,4,6-tri-O-acetyl-α-D-glucopyranosyl acetate 
• 116265-22-6 Benzyl-2,3,5,6-tetra-O-benzyl-7-O-(3,4,6-tri-O-acetyl-2-azido-2-desoxy-α-D-glucopyranosyl)-L-glycero-α-D-manno-heptofuranosid 

Relevant articles and documents

Building Units of Oligosaccharides, XCI. - Synthesis of Disaccharides from L-glycero-D-manno-Heptose and 2-Amino-2-deoxy-D-glucose

Coupling of 3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl bromide (9) with benzyl 2,3,5,6-tetra-O-benzyl-L-glycero-α-D-manno-heptofuranoside (10) gives in the presence of silver triflate stereoselectively the α-glycoside 12, in the presence of sil