116316-04-2Relevant academic research and scientific papers
Electrophilic azido selenenylation of alkenes. A simple synthetic route to racemic taxol side chain
Tiecco, Marcello,Testaferri, Lorenzo,Temperini, Andrea,Bagnoli, Luana,Marini, Francesca,Santi, Claudio
, p. 2167 - 2179 (2007/10/03)
Simple alkenes react with PhSeOTf and NaN3 in MeCN to afford β- phenylseleno azides as the result of a stereospecific trans addition. The regioselectivity of the process is determined by the structure of the alkene.
Novel Azido-phenylselenenylation of Double Bonds. Evidences for a Free Radical Process
Tingoli, Marco,Tiecco, Marcello,Chianelli, Donatella,Balducci, Roberta,Temperini, Andrea
, p. 6809 - 6813 (2007/10/02)
A simple and mild azido-phenylselenenylation of terminal alkenes, which proceeds with complete anti-Markovnikov regioselectivity, has been developed.This reaction occurs when the alkenes are treated with (diacetoxyiodo)benzene, sodium azide, and diphenyl
PHENYLSELENIUM AZIDE ADDITION TO ALKENES. A NEW AND STEREOSPECIFIC INTRODUCTION OF Se AND N INTO ORGANIC MOLECULES.
Hassner, Alfred,Amarasekara, Ananda S.
, p. 5185 - 5188 (2007/10/02)
The first examples of direct introduction of PhSe and N3 functions by addition to olefins are reported.The addition of PhSeN3 to simple alkenes, as well as to activated alkenes takes place in the absence of a catalyst.The reaction proceeds stereospecifica
