116386-41-5

Upstream product

• 87326-88-3 methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 87326-90-7 methyl 4-O-acetyl-2,3-di-O-benzyl-6-deoxy-α-D-xylo-hex-5-enopyranoside 
• 136458-74-7 2L-(2,4/3)-2-O-acetyl-3,4-di-O-benzyl-2,3,4-trihydroxy-5-cyclohexen-1-one 
• 127243-50-9 1D-(1,3/2,4)-3-O-acetyl-1,2-di-O-benzyl-5-cyclohexene-1,2,3,4-tetrol 
• 122777-37-1 1D-(1,3/2,4)-3-O-acetyl-1,2-di-O-benzyl-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol 
• 127213-12-1 1D-(1,3/2,4)-1,2-di-O-benzyl-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol 
• 122777-38-2 1D-(1,2,3/4)-2-azido-3,4-di-O-benzyl-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol 
• 127213-13-2 1D-(1,3/2,4)-1,2-di-O-benzyl-3-O-(methanesulfonyl)-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol 
• 122777-39-3 1D-(1,2,3/4)-3,4-di-O-benzyl-2-<(tert-butoxycarbonyl)amino>-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol 
• 85716-44-5 methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside 
• 1187828-00-7 (4S,5R,6S)-4,5,6-tris(benzyloxy)-2-methylcyclohex-2-enone 
• 1313193-64-4 (4S,5R,6S)-4,5,6-tris(benzyloxy)-2-iodocyclohex-2-en-1-one 
• 1313193-67-7 C₂₁H₂₀O₄ 
• 1313193-70-2 C₂₃H₂₄O₆ 
• 1313193-72-4 C₂₁H₂₂O₅ 

Relevant academic research and scientific papers

Highly diastereoselective Morita-Baylis-Hillman chemistry: A remote activation effect in the diastereoface selective synthesis of densely functionalized branched cyclic enones from d-glucose

A highly diastereoselective C-2 alkylation of sugar derived cyclic enone 1 in the presence of diethylaluminium iodide by utilizing Morita-Baylis-Hillman chemistry is reported. While diethylaluminium iodide was found to be a suitable Lewis acid for this tr

Syntheses of (-)-gabosine A, (+)-4-epi-gabosine A, (-)-gabosine E, and (+)-4-epi-gabosine e

(+)-4-epi-Gabosine A 1 and (-)-gabosine A 2 have been synthesized starting from methyl α,d-glucopyranoside and methyl α,d-mannopyranoside, respectively, by utilizing Pd(0) catalyzed Stille coupling as the key step. On the other hand, syntheses of (+)-4-ep

Total Synthesis of Hygromycin A

The first complete synthesis of antibiotic hygromycin A is reported; coupling of the protected sugar moiety (2) and the aminocyclitol (3) derived from D-glucose as the optically active form, followed by deprotection, gives the product (1) which was identi