122777-38-2

Upstream product

• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 
• 116386-41-5 (3S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-2-methylene-tetrahydro-pyran-3-ol 
• 127213-13-2 1D-(1,3/2,4)-1,2-di-O-benzyl-3-O-(methanesulfonyl)-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol 
• 87326-88-3 methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside 
• 127213-12-1 1D-(1,3/2,4)-1,2-di-O-benzyl-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol 
• 122777-37-1 1D-(1,3/2,4)-3-O-acetyl-1,2-di-O-benzyl-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol 
• 87326-90-7 methyl 4-O-acetyl-2,3-di-O-benzyl-6-deoxy-α-D-xylo-hex-5-enopyranoside 
• 127243-50-9 1D-(1,3/2,4)-3-O-acetyl-1,2-di-O-benzyl-5-cyclohexene-1,2,3,4-tetrol 
• 136458-74-7 2L-(2,4/3)-2-O-acetyl-3,4-di-O-benzyl-2,3,4-trihydroxy-5-cyclohexen-1-one 
• 110-87-2 3,4-dihydro-2H-pyran 

Downstream Products

• 122777-39-3 1D-(1,2,3/4)-3,4-di-O-benzyl-2-<(tert-butoxycarbonyl)amino>-1-O-tetrahydropyranyl-5-cyclohexene-1,3,4-triol 

Relevant academic research and scientific papers

Total Synthesis of Antibiotic Hygromycin A

The first total synthesis of the antibiotic (-)-hygromycin A (1) has been achieved by a coupling reaction of the sugar moiety (2) and the cyclitol moiety (3).Both components were synthesized in homochiral forms starting from D-glucose.This synthesis fully

Total Synthesis of Hygromycin A

The first complete synthesis of antibiotic hygromycin A is reported; coupling of the protected sugar moiety (2) and the aminocyclitol (3) derived from D-glucose as the optically active form, followed by deprotection, gives the product (1) which was identi