116417-80-2Relevant academic research and scientific papers
O-Glycosylation Enabled by N-(Glycosyloxy)acetamides
Liu, Miao,Li, Bo-Han,Xiong, De-Cai,Ye, Xin-Shan
, p. 8292 - 8303 (2018)
A novel glycosylation protocol has been established by using N-(glycosyloxy)acetamides as glycosyl donors. The N-oxyacetamide leaving group in donors could be rapidly activated in the presence of Cu(OTf)2 or SnCl4 under microwave irr
C -Glycosylation enabled by N -(glycosyloxy)acetamides
Li, Bo-Han,Li, Tian,Liu, Meng,Liu, Miao,Wu, Xia,Xiong, De-Cai,Ye, Xin-Shan
supporting information, p. 3043 - 3046 (2020/05/08)
The C-glycosylation of C-nucleophiles including allyltrimethylsilane, silyl enol ethers and phenols with N-(glycosyloxy)acetamides as glycosyl donors has been realized. This protocol provides a convenient and practical route for the synthesis of alkyl C-glycosides and aryl 2-deoxy-β-C-glycosides under mild reaction conditions.
Expedient synthesis of aminooxylated-carbohydrates for chemoselective access of glycoconjugates
Renaudet, Olivier,Dumy, Pascal
, p. 7575 - 7578 (2007/10/03)
Herein, we describe an efficient preparation of various biologically important carbohydrate motifs bearing an aminooxy group at the anomeric position. These nucleophilic sugar analogues represent useful intermediates for the chemoselective preparation of
The Synthesis of N-Glycosyloxyphthalimides via Mitsunobu Reaction
Grochowski, Edward,Nashed, Eugenia M.,Jurczak, Janusz
, p. 255 - 260 (2007/10/02)
The reaction of five reepresentative carbohydrate derivatives, containing a free anomeric hydroxy group, with N-hydroxyphthalimide (4) in the presence of triphenylphosphine (1) and diethyl azodicarboxylate (2) was investigated.In all cases the reaction af
