1164519-53-2Relevant academic research and scientific papers
Novel nickel(II) complexes for the catalytic copolymerization of ethylene and carbon monoxide: Polyketone synthesis in supercritical carbon dioxide
Klaeui, Wolfgang,Bongards, Jochen,Reiss, Guido J.
, p. 3894 - 3896 (2007/10/03)
The most effective nickel catalysts for the copolymerization of ethylene and carbon monoxide, to give polyketones, known to date are based on enaminone ligands. With a perfluorinated side chain these complexes (see, for example, 1) are soluble in supercritical carbon dioxide and catalyze the formation of polyketones in this medium.
Pyrrolidino enaminones structural related to gyrase inhibitors: Synthesis, cyclization and pharmacological activity
Dannhardt,Bauer
, p. 805 - 810 (2007/10/03)
The synthesis and stereochemical characteristics of pyrrolidino enaminones with structural analogy to quinolone antibacterial agents are reported. Retro-aldol reaction of the esters 7 is observed under all conditions of hydrolysis, the enzyme catalyzed re
