Cas 116454-01-4,(4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-carboxylic acid methyl ester

116454-01-4

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Basic information

Product Name: (4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-carboxylic acid methyl ester
Synonyms:
CAS NO:116454-01-4
Molecular Formula:
Molecular Weight: 580.678
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-carboxylic acid methyl ester(CAS DataBase Reference)
NIST Chemistry Reference: (4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-carboxylic acid methyl ester(116454-01-4)
EPA Substance Registry System: (4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-carboxylic acid methyl ester(116454-01-4)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 116454-01-4(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 116454-01-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,6,4,5 and 4 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 116454-01:
(8*1)+(7*1)+(6*6)+(5*4)+(4*5)+(3*4)+(2*0)+(1*1)=104
104 % 10 = 4
So 116454-01-4 is a valid CAS Registry Number.

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116454-01-4Relevant academic research and scientific papers

C-1 LITHIATION OF C-2 ACTIVATED GLUCALS

Schmidt, Richard,Preuss, Rainer,Betz, Rainer

, p. 6591 - 6594 (1987)

Direct lithiation of the readily available 2-benzyloxy and the 2-phenylthio glucals 1 and 7 at the anomeric carbon atom leads to intermediates reacting with different electrophiles.Subsequent removal of the phenylthio group in compounds 9a, b with Raney-nickel and distereospecific 1-hydrogen- and 2-hydroxy-transfer with the BH3*SMe2/H2O2, NaOH system provides a convenient entry into functionalized C-glucopyranosides.

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