Tetrahedron Letters p. 6591 - 6594 (1987)
Update date:2022-07-29
Topics:
Schmidt, Richard
Preuss, Rainer
Betz, Rainer
Direct lithiation of the readily available 2-benzyloxy and the 2-phenylthio glucals 1 and 7 at the anomeric carbon atom leads to intermediates reacting with different electrophiles.Subsequent removal of the phenylthio group in compounds 9a, b with Raney-nickel and distereospecific 1-hydrogen- and 2-hydroxy-transfer with the BH3*SMe2/H2O2, NaOH system provides a convenient entry into functionalized C-glucopyranosides.
View MoreContact:+86-710-3516804
Address:Number 83,Panggong road,Xiangcheng District,Xiangyang ,Hubei
Hangzhou Dingyan Chem Co., Ltd
website:http://www.dingyanchem.com
Contact:86-571-87157530
Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004
Chongqing KonAo Health Co.,Ltd
Contact:13687578375
Address:wuhan hubei china
Xinchang Jiu Xin Pharmaceutical Co., Ltd
website:http://www.jiuxinpharm.com
Contact:86 137 5756 8585
Address:Poyang industry Park
Shanghai Sinofluoro Scientific Co., Ltd
Contact:+86-21-64279360
Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
Doi:10.1002/cmdc.201500063
(2015)Doi:10.1016/0040-4039(88)85132-3
(1988)Doi:10.1021/ja9033582
(2009)Doi:10.1021/acs.joc.0c00344
(2020)Doi:10.1007/BF00769652
(1988)Doi:10.1021/ol503081b
(2014)
