116458-18-5Relevant academic research and scientific papers
Silylamines in organic synthesis: preparation and some reactions of N,C-dilithiosilylamines
Burns, Stephanie A.,Corriu, Robert J. P.,Huynh, Vilam,Moreau, Joel J. E.
, p. 281 - 290 (2007/10/02)
The dimetallation of some olefinic and aromatic N-trimethylsilylamines has been examined.Treatment with a two molar proportion of n-butyllithium gives organodimetallic reagents, which react with trimethylchlorosilane to give N,N,C-tris(trimethylsilyl)amines in 45 to 65percent yields.The dianonic reagent obtained from (trimethylsilyl)(allyl)amine reacts with benzoyl chloride, N,N-dimethylformamide, ethyl-2-furylcarboxylate, and benzil to give substituted pyrroles and pyridines.
