116467-77-7Relevant articles and documents
HYDROXYLATION OF BENZENES INVOLVING THE NIH SHIFT UTILIZING ELECTRONIC MODEL COMPOUND FOR MONOOXYGENASES
Kojo, Shosuke,Fukunishi, Koushi
, p. 1707 - 1710 (1983)
The reaction of anisole-4-(2)H or toluene-4-(2)H with 2-hydroperoxyhexafluoro-2-propanol gave corresponding phenols involving the NIH shift, the extent of which was 57percent and 51percent respectively.These values were very close to those of cytochrome P450.
ON THE MECHANISM OF AROMATIC HYDROXYLATION BY O(3P) ATOMS
Zadok, Elazor,Mazur, Yehuda
, p. 4955 - 4958 (2007/10/02)
It is shown that O(3P) oxidation of aromatic compounds in the liquid phase leading to phenols may involve the intermediacy of triplet diradicals