116491-10-2

Upstream product

• 63296-56-0 (S)-(benzyloxymethoxy)propanal 
• 21382-82-1 (carbethoxyethylidene)triphenylphosphorane 
• 3587-60-8 Benzyloxymethyl chloride 
• 63296-55-9 (S)-(-) ethyl 2-<(benzyloxy)ymethoxy>propanoate 

Downstream Products

• 86280-31-1 C₁₄H₁₈⁽²⁾H₂O₃ 
• 116491-11-3 (2S)-(3R)-(4S)-4-O-benzyloxymethoxy-2-C-methyl-5-deoxyxylonic acid ethyl ester 
• 116491-00-0 (2R)-(3S)-(4S)-4-O-benzyloxymethoxy-2-C-methyl-5-deoxyarabinonic acid ethyl ester 
• 86280-33-3 C₁₄H₁₇⁽²⁾H₃O₂ 
• 86280-32-2 C₁₄H₁₇⁽²⁾H₂ClO₂ 

Relevant academic research and scientific papers

CATALYTIC OSMYLATION OF ELECTRON POOR ALLYLIC ALCOHOLS AND ETHERS. A SYNTHETIC APPROACH TO BRANCHED CHAIN SUGARS

The catalytic osmylation of electron-poor allylic ethers and alcohols was studied.In the case of γ-alkoxy E-enoates reaction selectivity was found to range from 2:1 to 8:1 in favor of the arabino (2,3-syn - 3,4-anti) product, regardless of the double bond

THE STEREOSPECIFIC SYNTHESIS OF (S)-2-2H3>METHYL-2-METHYLBUTANOL. CHARACTERISATION OF THE (R) AND (S) ENANTIOMERS OF THE RACEMIC 2H3>ALCOHOL BY 2H-NMR IN THE PRESENCE OF A CHIRAL SHIFT REAGENT.

The synthesis of the title compound is described.Assigment have been made in the 2H-NMR spectrum for the 2H3>methyl resonances of racemic 2-2H3>methyl-2-methylbutanol which were rendered anisochronous by the presence of tris(3-heptafluorobutyryl-d-camphorato)europium(III).