116502-10-4

Upstream product

• 56917-71-6 5-trimethylsilyl-2-cyclohexanone 
• 106-45-6 para-thiocresol 

Downstream Products

• 116384-91-9 (3R,5S)-3-Methyl-3-p-tolyl-5-trimethylsilanyl-cyclohexanone 
• 116384-86-2 (3R,5S)-3-Methyl-3-phenyl-5-trimethylsilanyl-cyclohexanone 
• 116384-86-2 (3R,5R)-3-Methyl-3-phenyl-5-trimethylsilanyl-cyclohexanone 
• 116384-89-5 (3R,5S)-3-Methyl-3-phenethyl-5-trimethylsilanyl-cyclohexanone 
• 116384-87-3 (3S,5R)-3-Butyl-3-methyl-5-trimethylsilanyl-cyclohexanone 
• 142944-77-2 3-Phenethyl-5-trimethylsilanyl-cyclohex-2-enone 
• 116384-85-1 3-(4-Methoxy-phenyl)-5-trimethylsilanyl-cyclohex-2-enone 
• 116384-83-9 3-Hexyl-5-trimethylsilanyl-cyclohex-2-enone 
• 116384-81-7 3-Butyl-5-trimethylsilanyl-cyclohex-2-enone 
• 131110-61-7 3-Phenyl-5-trimethylsilanyl-cyclohex-2-enone 
• 116384-80-6 3-Methyl-5-trimethylsilanyl-cyclohex-2-enone 
• 116384-79-3 (+/-)-3-tolylthio-5-trimethylsilyl-2-cyclohexenone 

Relevant academic research and scientific papers

CONSTRUCTION OF CHIRAL QUARTERNARY CARBON CENTERS USING 3-SUBSTITUTED 5-TRIMETHYLSILYL-2-CYCLOHEXENONES: SYNTHESIS OF (+)-α-CUPARENONE

1,4-Addition of Grignard reagents to 3-substituted 5-trimethylsilyl-2-cyclohexenones proceeded in a highly diastereoselective manner.By utilizing the reaction, (+)-α-cuparenone was synthesized starting from enantiomerically pure 3-p-tolylthio-5-(trimethyl

(R)- AND (S)-5-TRIMETHYLSILYL-2-CYCLOHEXENONE: A VERSATILE CHIRAL SOURCE FOR THE SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXANONE DERIVATIVES

5-Trimethylsilyl-2-cyclohexenone was synthesized from anisole and was successfully resolved to the optically pure form utilizing kinetic resolution method of the reaction with thiol in the presence of cinchonidine. (+)-α-curcumene was synthesized from (R)