116503-99-2

Basic information

• Product Name: 3,3-dicinnamyl-6-methyl-2,4-pyrandione
• Synonyms: 3,3-dicinnamyl-6-methyl-2,4-pyrandione
• CAS NO: 116503-99-2
• Molecular Weight: 358.437
• Mol File: 116503-99-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,3-dicinnamyl-6-methyl-2,4-pyrandione(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3-dicinnamyl-6-methyl-2,4-pyrandione(116503-99-2)
• EPA Substance Registry System: 3,3-dicinnamyl-6-methyl-2,4-pyrandione(116503-99-2)

Safety Data

• Hazardous Substances Data: 116503-99-2(Hazardous Substances Data)

Upstream product

• 675-10-5 4-hydroxy-6-methyl-2-pyron 
• 21040-45-9 Cinnamyl acetate 

Relevant articles and documents

Palladium-Catalyzed C-Alkylations of the Highly Acidic and Enolic Triacetic Acid Lactone. Mechanism and Stereochemistry

4-Hydroxy-6-methyl-2-pyrone (triacetic acid lactone) (1) is efficiently alkylated at C-3 with primary and secondary allylic substrates under thermodynamic control by using palladium(0) catalysts.Controlled hydrogenation of the resulting allylated derivatives affords pyrones with saturated chains at C-3.Allylic alkylations occur with retention of configuration at the allylic center, probably through a reversible kinetically favored O-alkylation.