Journal of Organic Chemistry p. 5328 - 5335 (1988)
Update date:2022-08-04
Topics:
Moreno-Manas, Marcial
Ribas, Jordi
Virgili, Albert
4-Hydroxy-6-methyl-2-pyrone (triacetic acid lactone) (1) is efficiently alkylated at C-3 with primary and secondary allylic substrates under thermodynamic control by using palladium(0) catalysts.Controlled hydrogenation of the resulting allylated derivatives affords pyrones with saturated chains at C-3.Allylic alkylations occur with retention of configuration at the allylic center, probably through a reversible kinetically favored O-alkylation.
View MoreContact:86-21-50966856
Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
Jiaozuo Zhongwen Trading Coporation Limited
Contact:--
Address:East Renmin Road
Shandong united-rising pharmaceutical cooperation.,ltd.
Contact:008653187965009
Address:171No., Jing5 Road, Shizhong District, Jinan, China
Beijing Top Science biological technology co., LTD
Contact:+86-13439059536
Address:15-1705 jre three mile, Beijing 100000,CHINA
SHANGHAI GILEADER ADVANCE MATERIAL TECHNOLOGY CO.,LTD
website:http://www.tanguitech.com/contact.asp
Contact:+86-021-58692556
Address:No.6 Building,No. 668 Hengan RD Pudong,Shanghai
Doi:10.1002/anie.201504035
(2015)Doi:10.1039/c4ra10489g
(2014)Doi:10.1016/S0040-4039(01)00170-8
(2001)Doi:10.1016/j.tetlet.2009.02.074
(2009)Doi:10.1081/SCC-100000193
(2001)Doi:10.1021/je00055a039
(1989)
