116507-02-9Relevant academic research and scientific papers
PENTACO-ORDINATE ORGANOSILICON COMPOUNDS IN SYNTHESIS: ASYMMETRIC REDUCTION OF CARBONYL COMPOUNDS WITH HYDROSILANES CATALYZED BY CHIRAL BASES
Kohra, Shinya,Hayashida, Hisashi,Tominaga, Yoshinori,Hosomi, Akira
, p. 89 - 92 (1988)
Reduction of carbonyl compounds with trialkoxysilane can be readily catalyzed by alkoxides of alkali metal.A considerable high asymmetric induction takes place by use of optically active diolates or even N-lithio 2-amino alcoholates derived from optically
