Tetrahedron Letters p. 89 - 92 (1988)
Update date:2022-08-02
Topics: Asymmetric reduction Hydrosilanes Chiral Bases Carbonyl Compounds Organosilicon compounds
Kohra, Shinya
Hayashida, Hisashi
Tominaga, Yoshinori
Hosomi, Akira
Reduction of carbonyl compounds with trialkoxysilane can be readily catalyzed by alkoxides of alkali metal.A considerable high asymmetric induction takes place by use of optically active diolates or even N-lithio 2-amino alcoholates derived from optically
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