PENTACO-ORDINATE ORGANOSILICON COMPOUNDS IN SYNTHESIS: ASYMMETRIC REDUCTION OF CARBONYL COMPOUNDS WITH HYDROSILANES CATALYZED BY CHIRAL BASES

DOI: 10.1016/0040-4039(88)80024-8

Source and publish data:

Tetrahedron Letters p. 89 - 92 (1988)

Update date:2022-08-02

Topics: Asymmetric reduction Hydrosilanes Chiral Bases Carbonyl Compounds Organosilicon compounds

Authors:

Kohra, Shinya

Hayashida, Hisashi

Tominaga, Yoshinori

Hosomi, Akira

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Article abstract of DOI:10.1016/0040-4039(88)80024-8

Reduction of carbonyl compounds with trialkoxysilane can be readily catalyzed by alkoxides of alkali metal.A considerable high asymmetric induction takes place by use of optically active diolates or even N-lithio 2-amino alcoholates derived from optically

Full text of DOI:10.1016/0040-4039(88)80024-8

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