PENTACO-ORDINATE ORGANOSILICON COMPOUNDS IN SYNTHESIS: ASYMMETRIC REDUCTION OF CARBONYL COMPOUNDS WITH HYDROSILANES CATALYZED BY CHIRAL BASES

DOI: 10.1016/0040-4039(88)80024-8

Source and publish data:

Tetrahedron Letters p. 89 - 92 (1988)

Update date:2022-08-02

Topics: Asymmetric reduction Hydrosilanes Chiral Bases Carbonyl Compounds Organosilicon compounds

Authors:

Kohra, Shinya

Hayashida, Hisashi

Tominaga, Yoshinori

Hosomi, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(88)80024-8

Reduction of carbonyl compounds with trialkoxysilane can be readily catalyzed by alkoxides of alkali metal.A considerable high asymmetric induction takes place by use of optically active diolates or even N-lithio 2-amino alcoholates derived from optically

Full text of DOI:10.1016/0040-4039(88)80024-8

Products guided by the article

Product name:C₁₈H₂₀O₄^(2-)*2Li⁽¹⁺⁾

Cas No:116507-02-9

R&D Labs maybe for 116507-02-9

Allicon Pharmaceuticals,Inc.

Contact:+86-519-86339586，13584329896

Address:Changzhou Scientific and Education Park
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
Suzhou Kangrun Pharmaceutical, Inc

Contact:86-512-63912376，63913329

Address:Building 2, No. 2358 ,Chang'an Rd, Wujiang Economic Development Zone Pioneering park, china
Chen jie

Contact:027-87677569

Address:Room 2203, yujingmingmen Buidling One, xiongchu Road, wuhan city, hubei province, China

Relevant to this article

Metal-organic gels as functionalisable supports for catalysis

Doi:10.1039/b822104a
(2009)
Copper-catalyzed intermolecular thioamination of maleimides with thiols and formamides: A one-step construction of 3-Amino-4-Thiomaleimides using formamides as nitrogen sources

Doi:10.1055/s-0037-1610536
(2018)
A Novel synthesis of 1,3-oxazine-2,4-diones via a simple and efficient reaction of CO₂ with 2,3-allenamides

Doi:10.1021/ol9009046
(2009)
Friedlaender synthesis of poly-substituted quinolines in the presence of triethylammonium hydrogen sulfate [Et₃NH][HSO₄] as a highly efficient, and cost effective acidic ionic liquid catalyst

Doi:10.1002/jhet.683
(2011)
Bis(phenazine-1-carboxamides): Structure-activity relationships for a new class of dual topoisomerase I/II directed anticancer drugs

Doi:10.1021/jm990423f
(2000)
Doi:10.1039/jr9470000595
(1947)

Article Doi