116530-83-7

Basic information

• Product Name: 2-Ethylmethylcyclohexaneacetate
• Synonyms: 2-Ethylmethylcyclohexaneacetate
• CAS NO: 116530-83-7
• Molecular Weight: 184.279
• Mol File: 116530-83-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Ethylmethylcyclohexaneacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Ethylmethylcyclohexaneacetate(116530-83-7)
• EPA Substance Registry System: 2-Ethylmethylcyclohexaneacetate(116530-83-7)

Safety Data

• Hazardous Substances Data: 116530-83-7(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 82166-21-0 methyl cyclohexane 
• 583-60-8 2-Methylcyclohexanone 
• 2209-00-9 Ethyl 2-methylcyclohexylideneacetate 

Downstream Products

• 6906-14-5 2-(2-methyl-cyclohexyl)-ethanol 
• 6617-04-5 2-Methylcyclohexaneacetic acid 

Relevant articles and documents

Iron-Catalyzed Intermolecular Functionalization of Non-Activated Aliphatic C?H Bonds via Carbene Transfer

The modification of strong Csp3?H bonds via iron carbene intermediates under mild reaction conditions has been an important challenge with attractive prospective in organic synthesis. In this work, we show the efficient combination of an electrophilic iron catalyst with a lithium Lewis acid for the functionalization of strong Csp3?H bonds of cyclic and linear alkanes by the activation of commercially available ethyl diazoacetate (EDA). The reaction proceeds with good yields, under mild reaction conditions (40 °C) and large excess of substrate is not needed. In addition, excellent activity is observed in the cyclopropanation of challenging aliphatic olefins. (Figure presented.).

Stereochemical studies of alkyl methylcyclohexaneacetates with 13C NMR spectroscopy in relation to their attractiveness to the German cockroach

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