116556-76-4Relevant academic research and scientific papers
An efficient synthesis of 2,3-dideoxy-α,β-unsaturated carbohydrate enals by mixed Lewis acid (HfCl4 and ZnI2) catalyzed hydration of glycals
Saquib, Mohammad,Sagar, Ram,Shaw, Arun K.
, p. 1052 - 1056 (2006)
A new, efficient method has been developed for converting acyl-, arylalkyl- and alkyl-protected glycals into corresponding 2,3-dideoxy-α,β-unsaturated carbohydrate enals utilizing the in situ generated push-pull effect resulting from the synergistic combi
GLYCALS IN STEREOSPECIFIC SYNTHESIS. II. DI-O-BENZYL-L-ARABINAL AND DI-O-BENZOYL-L-ARABINAL IN THE SYNTHESIS OF SATURATED AND UNSATURATED TERMINAL EPOXIDES
Tolstikov, A. G.,Khakhalina, N. V.,Savateeva, E. E.,Spirikhin, L. V.,Odinokov, V. N.,Tolstikov, G. A.
, p. 706 - 710 (2007/10/02)
The acid opening of di-O-benzyl-L-arabinal and di-O-benzoyl-L-arabinal, catalyzed by mercuric sulfate, is the key stage in the synthesis of chiral dihydroxy compounds with selectively protected hydroxy functions.They were used for the production of saturated and unsaturated terminal epoxides, which are of potential interest as chiral units in the convergent synthesis of biologically active compounds.
Benzyl Esters of D- and L-Arabinals as Chiral Synthons in Organic Synthesis
Tolstikov, A. G.,Khakhalina, N. V.,Spirikhin, L. V.
, p. 221 - 222 (2007/10/02)
An acidic opening of the benzyl esters of D and L arabinal (1,5-anhydro-2-deoxy-erythro-pent-1-enitol) catalyzed by mercuric sulfate has been proposed as the key step in the preparation of chiral synthons with selectively substituted hydroxy groups.
