116556-82-2Relevant academic research and scientific papers
GLYCALS IN STEREOSPECIFIC SYNTHESIS. II. DI-O-BENZYL-L-ARABINAL AND DI-O-BENZOYL-L-ARABINAL IN THE SYNTHESIS OF SATURATED AND UNSATURATED TERMINAL EPOXIDES
Tolstikov, A. G.,Khakhalina, N. V.,Savateeva, E. E.,Spirikhin, L. V.,Odinokov, V. N.,Tolstikov, G. A.
, p. 706 - 710 (2007/10/02)
The acid opening of di-O-benzyl-L-arabinal and di-O-benzoyl-L-arabinal, catalyzed by mercuric sulfate, is the key stage in the synthesis of chiral dihydroxy compounds with selectively protected hydroxy functions.They were used for the production of saturated and unsaturated terminal epoxides, which are of potential interest as chiral units in the convergent synthesis of biologically active compounds.
Benzyl Esters of D- and L-Arabinals as Chiral Synthons in Organic Synthesis
Tolstikov, A. G.,Khakhalina, N. V.,Spirikhin, L. V.
, p. 221 - 222 (2007/10/02)
An acidic opening of the benzyl esters of D and L arabinal (1,5-anhydro-2-deoxy-erythro-pent-1-enitol) catalyzed by mercuric sulfate has been proposed as the key step in the preparation of chiral synthons with selectively substituted hydroxy groups.
