116557-72-3

Upstream product

• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 151-10-0 1,3-Dimethoxybenzene 
• 29418-46-0 (2,4-dimethoxy-phenyl)-phenyl-diazene 
• 98-59-9 p-toluenesulfonyl chloride 
• 2735-04-8 2,4-Dimethoxyaniline 

Downstream Products

• 721401-09-8 2,4-dimethoxy-N-methyl-5-nitro-aniline 
• 858243-72-8 formic acid-(2,4-dimethoxy-N-methyl-5-nitro-anilide) 
• 859492-41-4 toluene-4-sulfonic acid-(2,4-dimethoxy-N-methyl-5-nitro-anilide) 
• 859492-47-0 toluene-4-sulfonic acid-(2,4-dimethoxy-N-methyl-anilide) 
• 859492-36-7 toluene-4-sulfonic acid-(2,4-dimethoxy-5-nitro-anilide) 

Relevant academic research and scientific papers

Phosphine-catalyzed intramolecular Rauhut-Currier reaction: Enantioselective synthesis of hydro-2: H -indole derivatives

A highly enantioselective intramolecular Rauhut-Currier reaction catalyzed by a multifunctional chiral aminophosphine catalyst was reported. A series of hydro-2H-indole derivatives that bear an all-carbon quaternary center were obtained in high yields (up to 94%), and excellent diastereo- and enantioselectivities (up to >20:1 dr and >99% ee). And this reaction could be performed on a gram scale using 2 mol% catalyst loading.

Oxidation-resistant, sterically demanding phenanthrolines as supporting ligands for copper(I) nitrene transfer catalysts

New 1,10-phenanthroline ligands have been synthesized with C 6F5- or 2,4,6-(CF3)3C 6H2- groups in the 2- and 9-positions; a cationic copper(I) complex of the latter catalyses nitrene transfer to the C-H bonds of electron-rich arenes.