55962-05-5

Basic information

• Product Name: [N-(p-Toluenesulfonyl)imino]phenyliodinane
• Synonyms: [N-(p-Toluenesulfonyl)imino]phenyliodinane;[N-(p-tolylsulfonyl)imino]phenyliodinane
• CAS NO: 55962-05-5
• Molecular Formula: C₁₃H₁₂INO₂S
• Molecular Weight: 375.23
• Mol File: 55962-05-5.mol
• Article Data: 40

Chemical Properties

• Melting Point: 104.0-105.0 °C (decomp)
• Appearance: /
• CAS DataBase Reference: [N-(p-Toluenesulfonyl)imino]phenyliodinane(CAS DataBase Reference)
• NIST Chemistry Reference: [N-(p-Toluenesulfonyl)imino]phenyliodinane(55962-05-5)
• EPA Substance Registry System: [N-(p-Toluenesulfonyl)imino]phenyliodinane(55962-05-5)

Safety Data

• Hazardous Substances Data: 55962-05-5(Hazardous Substances Data)

Usage

General Description

[N-(p-Toluenesulfonyl)imino]phenyliodinane, also known as PhI=NTs, is a powerful and selective reagent used in organic synthesis for the conversion of alcohols to aldehydes or ketones. It is a versatile and reactive oxidizing agent that is commonly used in synthetic chemistry due to its mild reaction conditions and high selectivity. PhI=NTs is particularly useful for the oxidation of primary and secondary alcohols, and it has been widely applied in the functionalization and modification of organic compounds. Its unique structure and reactivity make it a valuable tool in the development of complex organic molecules in the field of organic synthesis.

Upstream product

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Downstream Products

• 146041-79-4 9-(toluene-4-sulfonyl)-9-aza-bicyclo[6.1.0]nonane 
• 118157-82-7 (Z)-N-(cyclooct-2-en-1-yl)-4-methylbenzenesulfonamide 
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• 70-55-3 toluene-4-sulfonamide 
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• 591-50-4 iodobenzene 
• 17879-98-0 trans-N-(p-toluenesulfonyl)-2,3-diphenylaziridine 
• 668994-46-5 cis-N-(p-toluenesulfonyl)-2,3-diphenylaziridine 
• 147054-74-8 N-(p-toluenesulfonyl)-2,3-diphenylaziridine 
• 1150-31-8 N-octyl-4-methylbenzenesulfonamide 
• 4083-64-1 Tosyl isocyanate 
• 50468-24-1 ethyl 3-phenyl-1-tosylaziridine-2-carboxylate 
• 160246-68-4 4-acetyl-3-hydroxy-2-phenyliodonio-phenolate 
• 21992-47-2 S-ethyl-S-methyl-N-(toluene-4-sulfonyl)-sulfimide 

Relevant articles and documents

Mechanistic studies of copper-catalyzed alkene aziridination

The mechanism of the copper-catalyzed aziridination of alkenes using [N-(p-toluenesulfonyl)imino]-phenyliodinane (PhINTs) as the nitrene source has been elucidated by a combination of hybrid density functional theory calculations (B3LYP) and kinetic exper

Method for preparing azabicyclic compounds

The method comprises the following steps: a compound of the formula II and a compound of the formula III react under the action of a Lewis acid [3 + 2], the azabicyclic compound represented by the formula I is obtained, and the reaction formula is as shown below. The method has the advantages of wide substrate adaptability range, mild reaction conditions, less reaction steps, high atom economy, high yield and stereoselectivity and the like.

Ni-Catalyzed Carboxylation of Aziridines en Route to β-Amino Acids

A Ni-catalyzed reductive carboxylation of N-substituted aziridines with CO2 at atmospheric pressure is disclosed. The protocol is characterized by its mild conditions, experimental ease, and exquisite chemo- and regioselectivity pattern, thus unlocking a new catalytic blueprint to access β-amino acids, important building blocks with considerable potential as peptidomimetics.