116565-15-2Relevant articles and documents
Hydroxyselenation of acetoxycyclohex-2-ene
Haughan, Alan F.,Knight,Sweeney
, p. 1781 - 1784 (1994)
The reaction of acetoxycyclohexene with N-phenylselenophthalimide in the presence of water is non-regiospecific, in contrast to the previously reported chloroselenation reaction.
Copper-Catalyzed Amidation of Primary and Secondary Alkyl Boronic Esters
Mori-Quiroz, Luis M.,Shimkin, Kirk W.,Rezazadeh, Sina,Kozlowski, Ryan A.,Watson, Donald A.
, p. 15654 - 15658 (2016/10/25)
The oxidative copper-catalyzed cross-coupling of functionalized alkyl boronic esters with primary amides is reported. Through the identification of appropriate diketimine ligands, conditions for efficient coupling of both primary and secondary alkyl boronic esters with diverse primary amides, including acetamide, have been developed.
Hydroxyselanylation of acyloxycyclohex-3-enes
Sweeney,Haughan, Alan F.,Knight,Thobhani, Smita
, p. 2729 - 2737 (2007/10/03)
In contrast to the corresponding hydroxyiodination reactions, the reaction of acetoxycyclohex-2-ene 1 with N-PSP in the presence of water shows little regiocontrol, but is highly diastereoselective. However, the same reaction of the (R)-phenylglycinate de
Process for preparing the enantiomeric forms of cis-configured 1,3-cyclohexanediol derivatives
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Page 29, (2010/02/08)
Process for preparing the enantiomeric forms of cis-configured 1,3-cyclohexanediol derivatives A process is described for preparing chiral, nonracemic, cis-configured 1,3-disubstituted cyclohexanols of the formula (I) where the radicals are as defined, by
Rhodium(I)- and iridium(I)-catalyzed hydroboration reactions: Scope and synthetic applications
Evans, David A.,Fu, Gregory C.,Hoveyda, Amir H.
, p. 6671 - 6679 (2007/10/02)
A study of the rhodium(I)- and iridium(I)-catalyzed hydroboration of olefins with catecholborane is described. Applications to organic synthesis were one focus of this investigation. The scope of the reaction was defined, and issues of stereoselection were addressed. The rhodium-catalyzed hydroboration of several classes of allylic alcohols was found to be highly diastereoselective, preferentially affording the isomer complementary to that furnished by the uncatalyzed variant of the reaction (9-BBN). The first two general approaches to effecting a directed olefin hydroboration were developed. Both phosphinites and amides proved capable of delivering the transition metal reagent.
