1165802-07-2Relevant academic research and scientific papers
Unsymmetrically Bridged Methyl Groups as Intermediates in the Transformation of Bridging Methylene to Bridging Acetyl Groups: Ligand Migrations and Migratory Insertions in Mixed Iridium/Ruthenium Complexes
Samant, Rahul G.,Trepanier, Steven J.,Wigginton, James R.,Xu, Li,Bierenstiel, Matthias,McDonald, Robert,Ferguson, Michael J.,Cowie, Martin
, p. 3407 - 3420 (2009)
Protonation of the methylene-bridged, tetracarbonyl species [IrRu(CO) 4(μ-CH2)(dppm)2][X] (X) CF 3SO3, BF4)(1)at - 90 ° C yields the methyl-bridged product [IrRu(CO)4(μ-CH3
