116616-48-9

Upstream product

• 34713-70-7 2-Phenylpropanal 
• 114341-93-4 3-(2-bromopropionyl)-4,4-dibuthyl-5,5-pentamethylene-2-oxazolidone 

Downstream Products

• 72691-75-9 Methyl (2S^*,3R^*,4R^*)-3-hydroxy-2-methyl-4-phenylvalerate 
• 72691-74-8 Methyl (2R^*,3S^*,4R^*)-3-hydroxy-2-methyl-4-phenylvalerate 

Relevant academic research and scientific papers

A HIGHLY STEREOSELECTIVE SYNTHESIS OF ALDOLS EMPLOYING THE REFORMATSKY REACTION OF 3-(2-BROMOPROPIONYL)-2-OXAZOLIDONE DERIVATIVES WITH VARIOUS ALDEHYDES

The title reactions of sterically crowded 2-oxazolidone derivatives with achiral aldehydes in the presence of zinc dust were found to give various 2,3-syn-aldols as major products (at most, 2,3-syn:2,3-anti=98:2).While a 2,3-syn-3,4-syn-aldol could be sim

HIGHLY STEREOSELECTIVE REFORMATSKY REACTIONS OF 3-(2-BROMOPROPIONYL)-2-OXAZOLIDONE DERIVATIVES WITH VARIOUS ALDEHYDES

The Reformatsky reactions of 3-(2-bromopropionyl)-2-oxazolidone derivatives with various aldehydes were investigated to elucidate the effects of substituents in the 2-oxazolidone moieties on their diastereoselectivities.The highest 2,3-syn-diastereoselect