A HIGHLY STEREOSELECTIVE SYNTHESIS OF ALDOLS EMPLOYING THE REFORMATSKY REACTION OF 3-(2-BROMOPROPIONYL)-2-OXAZOLIDONE DERIVATIVES WITH VARIOUS ALDEHYDES

DOI: 10.1016/S0040-4039(00)96931-4

Source and publish data:

Tetrahedron Letters p. 6629 - 6632 (1987)

Update date:2022-07-29

Topics:

Authors:

Ito, Yoshio

Terashima, Shiro

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Article abstract of DOI:10.1016/S0040-4039(00)96931-4

The title reactions of sterically crowded 2-oxazolidone derivatives with achiral aldehydes in the presence of zinc dust were found to give various 2,3-syn-aldols as major products (at most, 2,3-syn:2,3-anti=98:2).While a 2,3-syn-3,4-syn-aldol could be sim

Full text of DOI:10.1016/S0040-4039(00)96931-4

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