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Pyridine, 1,4-dihydro-4-[[(4-methylphenyl)sulfonyl]phenylmethylene]-1-(trimethylsil yl)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

116665-07-7

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116665-07-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 116665-07-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,6,6,6 and 5 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 116665-07:
(8*1)+(7*1)+(6*6)+(5*6)+(4*6)+(3*5)+(2*0)+(1*7)=127
127 % 10 = 7
So 116665-07-7 is a valid CAS Registry Number.

116665-07-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,4-dihydro-4-<α-(4-methylphenylsulfonyl)benzylidene>-1-(trimethylsilyl)pyridine

1.2 Other means of identification

Product number -
Other names 4-[Phenyl-(toluene-4-sulfonyl)-methylene]-1-trimethylsilanyl-1,4-dihydro-pyridine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:116665-07-7 SDS

116665-07-7Downstream Products

116665-07-7Relevant academic research and scientific papers

Remote controlled nucleophilicity, 2: Lithiated C(α)-substituted 4-methylpyridines

Anders,Opitz,Bauer

, p. 1221 - 1227 (1991)

C(α)-substituted 4-methylpyridines have been N-lithiated and reacted with chlorotrimethylsilane and other electrophiles. The lithiated C(α)-NMe2 substituted intermediate shows an interesting dichotomy of behavior towards electrophiles: It represents the borderline between compounds for which an extreme N or C(α) regionucleophilicity is observed.

"Remote Controlled" Nucleophilicity of Anions of some 4-Alkylpyridines: AM 1- and MNDO-Calculations, Experimental Tests

Anders, Ernst,Korn, Uwe,Stankowiak, Achim

, p. 105 - 112 (2007/10/02)

The easily accessible pyridines 10 are transformed into sodium salts 12a-c by reaction with sodium bis(trimethylsilyl)amide (11).With electrophiles 13, the salts 12 usually react to give N-substituted 4-alkylidene-1,4-dihydropyridines 5a-f.This reaction b

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