116668-06-5

Basic information

• Product Name: cis-bis(N,N'-di-p-tolyltriazene)bis(pentafluorophenyl)palladium(II)
• CAS NO: 116668-06-5
• Molecular Weight: 891.122
• Mol File: 116668-06-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-bis(N,N'-di-p-tolyltriazene)bis(pentafluorophenyl)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: cis-bis(N,N'-di-p-tolyltriazene)bis(pentafluorophenyl)palladium(II)(116668-06-5)
• EPA Substance Registry System: cis-bis(N,N'-di-p-tolyltriazene)bis(pentafluorophenyl)palladium(II)(116668-06-5)

Safety Data

• Hazardous Substances Data: 116668-06-5(Hazardous Substances Data)

Upstream product

• 74436-10-5 (NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2 
• 785-86-4 1,3-di(p-tolyl)triaz-1-ene 

Relevant articles and documents

Synthesis and reactivity of palladium complexes with N,N'-di-p-tolyl-formamidine, -triazene or -formamidinato ligands. Insertion of CNC6H4Me-p, CS2 or CO2 into a Pd-N bond

The syntheses of complexes containing the HL ligands N,N'-di-p-tolylformamidine (TolNCHNHTol) (Tol=p-MeC6H4) and N,N'-di-p-tolyltriazene (TolNNNHTol) are described.The complexes are of the types cis-, trans- and cis-, with the HL ligands acting as monodentate ligands via the imino N atom.A N,N'-di-p-tolylformamidinato complexes, is also described.It undergoes irreversible insertion of CNTol of CS2, or reversible insertion of CO2, into one N-Pd bond.While the CS2 insertion product is an S,S-bonded dithiocarbamate-type complex, the product arising from the CO2 insertion contains a six-membered palladiacycle with the ligand O,N-bonded to the Pd atom.