74436-10-5

Upstream product

• 1643-19-2 tetrabutylammomium bromide 
• 344-04-7 bromopentafluorobenzene 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 1076-44-4 pentafluorophenyl lithium 
• 7550-35-8 lithium bromide 
• 10025-98-6 potassium tetrachloropalladate(II) 
• 1076-44-4 Li⁽¹⁺⁾*C₆F₅^(1-)=Li(C₆F₅) 

Downstream Products

• 1923-70-2 tetrabutylammonium perchlorate 
• 116722-40-8 N(C₄H₉)4⁽¹⁺⁾*[Pd(C₆F₅)2(S₂CN(C₆H₄CH₃)CHNC₆H₄CH₃)]^(1-)=[N(C₄H₉)4][Pd(C₆F₅)2(S₂CN(C₆H₄CH₃)CHNC₆H₄CH₃)] 
• 81027-45-4 cis-[Pd(C₆F₅)2(CNBu-t)2] 
• 81075-97-0 cis-[Pd(C₆F₅)2(CNTol)2] 

Relevant academic research and scientific papers

Synthesis, Molecular Structure and Reactivity of cis-1,κN)> a Compound displaying an Unusual η1 Arene-Palladium Interaction

The reaction between cis- (thf = tetrahydrofuran) and benzyldimethylamine rendered cis-1,κN)> 1, a four-co-ordinate compound containing as unusual η1 arene-palladium interaction with the benzyldimethylamine acting as a bidentate chelating ligand.Complex 1 reacts with acetone, acetonitrile, dimethyl sulfoxide or CO (L) to yield cis- 2-5 respectively, which do not have a η1 arene-palladium interaction.The reaction of 1 with Br(1-) or SPMe2Ph (L') (molar ratio 1:1) produced the complete displacement of the amine and the formation of (n-) (n = 2 or 0), and with Cl(1-) (molar ratio 1:1) a mixture of complexes is formed.The crystal structures of compounds 1 and 2 have been determined.

Mono- and Bi-nuclear Anionic Pentafluorophenyl Complexes of Palladium(II) and Platinum(II)

The arylation of K2, , MCl2, or 2 (M=Pd or Pt; tht=tetrahydrothiophen) with LiR or MgBrR (R=C6F5) leads to novel mono- and bi-nuclear anionic organo-derivatives of the general formulae -, su