116671-48-8

Basic information

• Product Name: 5-Phenylsulfanyl-hept-6-en-3-one
• CAS NO: 116671-48-8
• Molecular Weight: 220.335
• Mol File: 116671-48-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-Phenylsulfanyl-hept-6-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Phenylsulfanyl-hept-6-en-3-one(116671-48-8)
• EPA Substance Registry System: 5-Phenylsulfanyl-hept-6-en-3-one(116671-48-8)

Safety Data

• Hazardous Substances Data: 116671-48-8(Hazardous Substances Data)

Upstream product

• 5296-64-0 allyl phenyl thioether 
• 69567-06-2 (N-methylanilino)prop-2-enenitrile 
• 75-03-6 ethyl iodide 

Relevant articles and documents

The Addition of 1-Lithio-1-(phenylthio)alkanes to 2-(N-Methylanilino)acrylonitrile: An Easy Access to 3-(Phenylthio)ketones and 2-Enones

A simple and versatile strategy for the synthesis of the title compounds is described.The key-step consists in the addition of 1-lithio-1-(phenylthio)alkanes to 2-(N-methylanilino)acrylonitrile, the nucleophilic phenylthioalkylation of an enol-cation equivalent.Alkylation of the adducts and hydrolysis give 3-(phenylthio)ketones, which can be isolated, or without further purification can be transformed into 2-enones via the well known oxidation-elimination procedure.These reactions are possible with allylic derivatives too, therefore the homologous vinylic compoundscan be prepared by the same way.Pyrolysis of the 1-lithioaminonitriles formed within the first step gives aminonitriles of cyclopropanones via cyclization.