1166841-75-3

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 155751-23-8 (R)-5-(hydroxymethyl)-2-cyclohexen-1-one 
• 1375467-35-8 (R)-3-(tert-butyldiphenylsilanyloxymethyl)-hex-5-enenitrile 
• 1375467-34-7 (S)-methanesulfonic acid 2-(tert-butyldiphenylsilanyloxymethyl)-pent-4-enyl ester 
• 1375467-38-1 (R)-5-(tert-butyldiphenylsilanyloxymethyl)-octa-1,7-dien-3-one 
• 1375467-37-0 5-(tert-butyldiphenylsilanyloxymethyl)-octa-1,7-dien-3-ol 
• 1375467-36-9 (R)-3-(tert-butyldiphenylsilanyloxymethyl)-hex-5-enal 

Downstream Products

• 1166841-76-4 (2R,3R,5R)-5-(tert-butyl-diphenyl-silyloxymethyl)-2,3-dihydroxy-cyclohexanone 
• 1190114-70-5 (R)-2-bromo-5-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohex-2-enone 
• 1168139-99-8 (1R,2S,3R,5S)-5-(hydroxymethyl)cyclohexane-1,2,3-triol 
• 1169708-41-1 (1R,2R,3R,5R)-5-(hydroxymethyl)cyclohexane-1,2,3-triol 
• 1375467-39-2 (1R,2S,3R,5S)-5-(tert-butyldiphenylsilyloxymethyl)cyclohexane-1,2,3-triol 
• 1375467-40-5 (1S,2R,4R,6R)-4-(tert-butyldiphenylsilyloxymethyl)bicyclo[4.1.0]heptan-2-ol 
• 1375467-42-7 (1S,5R)-5-(tert-butyldiphenylsilyloxymethyl)cyclohex-2-enol 
• 1375467-43-8 (1S,2S,4S,6R)-4-(tert-butyldiphenylsilyloxymethyl)-7-oxa-bicyclo[4.1.0]heptan-2-ol 
• 1376197-39-5 (1S,2S,3S,5S)-5-(tert-butyldiphenylsilyloxymethyl)cyclohexane-1,2,3-triol 
• 1376197-44-2 (1S,2S,3S,5S)-5-(hydroxymethyl)cyclohexane-1,2,3-triol 
• 1375467-44-9 (1R,2S,4R,6S)-4-(tert-butyldiphenylsilyloxymethyl)bicyclo[4.1.0]heptan-2-ol 
• 1375467-47-2 C₂₉H₄₄O₃Si₂ 
• 1376197-50-0 (1S,2R,3R,5R)-5-(hydroxymethyl)cyclohexane-1,2,3-triol 
• 1395386-77-2 C₂₃H₃₂O₄Si 

Relevant academic research and scientific papers

Stereoselective synthesis of a novel natural carbasugar and analogues from hydroxymethylated cycloalkenone scaffolds

Novel carbasugars from Streptomyces lincolnensis have been synthesized from an enantiomerically pure 5-hydroxymethyl-cyclohex-2-enone scaffold via a stereoselective approach. Several structural analogues of those carbasugars have also been synthesized in a stereoselective manner from hydroxymethylated cycloalkenone derivatives.

Asymmetric synthesis of hydroxy-skipped bishomo-inositols as potential glycosidase inhibitors

Four isomeric hydroxy-skipped bishomo-inositol analogs have been synthesized from both enantiomers of 5-hydroxymethyl-2-cyclohexenone. Sharpless asymmetric dihydroxylation and substrate-directed anionic hydroxymethylation are the key reactions which have

Asymmetric synthesis of palitantin by an enzymatic and organocatalytic approach

The natural enantiomer of the fungal metabolite (+)-palitantin has been synthesized by adopting a chemoenzymatic and organocatalytic approach. Lipase catalyzed kinetic resolution, Sharpless asymmetric dihydroxylation and organocatalytic asymmetric hydroxy

Chemo-enzymatic asymmetric total synthesis of penienone

An asymmetric synthesis of penienone has been accomplished from (R)-5-hydroxymethyl-2-cyclohexenone by adopting a linear strategy. Lipase-PS-catalyzed enzymatic kinetic resolution (EKR) and Julia-Kocienski olefination followed by substrate-directed anioni