155751-23-8

Upstream product

• 155751-19-2 (R)-5-Hydroxymethyl-3-methoxymethoxy-cyclohex-2-enone 
• 108-05-4 vinyl acetate 
• 84011-70-1 1-oxo-5-hydroxy-methyl-2-cyclohexene 
• 63723-94-4 3-ethoxy-5-carbethoxy-2-cyclohexenone 
• 42858-60-6 3,5-cyclohexanedione-1-carboxylic acid 
• 155702-97-9 5-Hydroxymethyl-3-methoxymethoxy-cyclohex-2-enone 

Downstream Products

• 179603-14-6 (R)-5-acetoxymethylcyclohex-2-en-1-one 
• 1166841-75-3 (R)-5-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohex-2-enone 
• 1256356-01-0 (R)-5-(4-methoxybenzyloxymethyl)cyclohex-2-enone 
• 130256-40-5 (R)-5-benzyloxymethyl-2-cyclohexenone 

Relevant academic research and scientific papers

Divergent Total Syntheses of (?)-Huperzine Q, (+)-Lycopladine B, (+)-Lycopladine C, and (?)-4-epi-Lycopladine D

We report herein our synthetic efforts towards the divergent syntheses of (?)-huperzine Q (1), (+)-lycopladine B (2), (+)-lycopladine C (3), and (?)-lycopladine D (4). The 10-step total synthesis of (?)-huperzine Q (1) and the first total syntheses of (+)

Total syntheses of (-)-huperzine Q and (+)-lycopladines B and C

Utilizing a late-stage enamine bromofunctionalization strategy, the twelve-step total synthesis of (-)-huperzine Q was accomplished. Furthermore, the first total syntheses of (+)-lycopladines B and C are described. An unprecedented X-ray crystal structure

Chemo-enzymatic asymmetric total synthesis of penienone

An asymmetric synthesis of penienone has been accomplished from (R)-5-hydroxymethyl-2-cyclohexenone by adopting a linear strategy. Lipase-PS-catalyzed enzymatic kinetic resolution (EKR) and Julia-Kocienski olefination followed by substrate-directed anioni

Asymmetric synthesis of palitantin by an enzymatic and organocatalytic approach

The natural enantiomer of the fungal metabolite (+)-palitantin has been synthesized by adopting a chemoenzymatic and organocatalytic approach. Lipase catalyzed kinetic resolution, Sharpless asymmetric dihydroxylation and organocatalytic asymmetric hydroxy

Efficient synthesis of optically active cyclohexenones

Optically active 5-hydroxymethylcyclohexenones and 5- acetoxymethylcyclohexenones were efficiently obtained by enzymatic enantioselective esterification and chemical conversion.