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1166994-78-0

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  • 11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct, min. 98% o-MeO-KITPHOS

    Cas No: 1166994-78-0

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  • 11-Dicyclohexylphosphino-12-(2-methoxyphenyl)-9,10-ethenoanthracene dichloromethane adduct, min. 98% o-MeO-KITPHOS

    Cas No: 1166994-78-0

  • No Data

  • No Data

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  • Strem Chemicals, Inc.
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1166994-78-0 Usage

Reaction

Useful ligand for the Palladium-catalyzed amination reaction. Useful ligand for Gold(I)-triflimide catalyzed intramolecular cyclizations.

Check Digit Verification of cas no

The CAS Registry Mumber 1166994-78-0 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,6,6,9,9 and 4 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1166994-78:
(9*1)+(8*1)+(7*6)+(6*6)+(5*9)+(4*9)+(3*4)+(2*7)+(1*8)=210
210 % 10 = 0
So 1166994-78-0 is a valid CAS Registry Number.

1166994-78-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 11-(dicyclohexylphosphino)-12-(2-methoxyphenyl)-9,10-dihydro-9,10-ethenoanthracene

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1166994-78-0 SDS

1166994-78-0Relevant articles and documents

Electron-rich, bicyclic biaryl-like KITPHOS monophosphines via [4+2] cycloaddition between 1-alkynylphosphine oxides and anthracene: Highly efficient ligands for palladium-catalysed C-N and C-C bond formation

Doherty, Simon,Knight, Julian G.,Smyth, Catherine H.,Jorgenson, Graeme A.

supporting information; experimental part, p. 1801 - 1806 (2009/07/25)

Electron-rich, bicyclic biaryl-like KITPHOS monophosphines have been prepared via Diels-Alder cycloaddition between 1-alkynylphosphine oxides and anthracene in an operationally straightforward and highly modular synthetic protocol that will allow access to an architecturally and electronically diverse family of ligands. Palladium complexes of these ligands are highly efficient catalysts for the Buchwald-Hartwig amination and Suzuki-Miyaura coupling of a wide range of aryl chlorides, which for the vast majority of substrate combinations outperform their o-(dicyclohexylphosphino) biphenyl-based counterparts.

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