5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one is an alkaloid with a similar structure to Nerinine, found in Nerine krigeii. It can be crystallized from AcOEt and is dextrorotatory with a specific rotation of +161.6° (c 0.57, CHC13). 5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one is hygroscopic and exhibits monoacidic base properties, yielding a picrate as yellow prisms with a melting point of 205-209°C (dec.), a methiodide with a melting point of 260-265°C (dec.), and a crystalline O-acetate with a melting point of 201-202°C. It contains a lactone ring that can be opened by alkalies and regenerated by acids.
1167-58-4
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Basic information
- Product Name: 5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one
- Synonyms: 5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one;Neronine
- CAS NO:1167-58-4
- Molecular Formula: C18H19NO6
- Molecular Weight: 345.34656
- EINECS: N/A
- Product Categories: N/A
- Mol File: 1167-58-4.mol
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Chemical Properties
- Melting Point: N/A
- Boiling Point: N/A
- Flash Point: N/A
- Appearance: /
- Density: N/A
- Refractive Index: N/A
- Storage Temp.: N/A
- Solubility: N/A
- CAS DataBase Reference: 5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one(CAS DataBase Reference)
- NIST Chemistry Reference: 5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one(1167-58-4)
- EPA Substance Registry System: 5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one(1167-58-4)
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Safety Data
- Hazard Codes: N/A
- Statements: N/A
- Safety Statements: N/A
- WGK Germany:
- RTECS:
- HazardClass: N/A
- PackingGroup: N/A
- Hazardous Substances Data: 1167-58-4(Hazardous Substances Data)
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1167-58-4 Usage
Uses
Used in Pharmaceutical Industry:5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one is used as a pharmaceutical compound for its potential therapeutic applications. Its unique structure and properties may contribute to the development of new drugs or drug candidates for various medical conditions.
Used in Chemical Research:
This alkaloid is used as a subject of chemical research to study its properties, reactions, and potential applications in various fields. Its lactone ring and ability to form different derivatives make it an interesting compound for further investigation and development.
Used in Natural Product Chemistry:
5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one is used in the study of natural products, particularly in the context of alkaloids and their potential biological activities. Its presence in Nerine krigeii provides insights into the chemical diversity of natural sources and their potential applications in medicine and other industries.
References
Briggs et at., J. Arner. Chern. Soc., 78,2899 (1956)Jeffs, Hawksworth., Tetrahedron Lett., 217 (1963)Check Digit Verification of cas no
The CAS Registry Mumber 1167-58-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,6 and 7 respectively; the second part has 2 digits, 5 and 8 respectively.Calculate Digit Verification of CAS Registry Number 1167-58:
(6*1)+(5*1)+(4*6)+(3*7)+(2*5)+(1*8)=74
74 % 10 = 4
So 1167-58-4 is a valid CAS Registry Number.
1167-58-4Upstream product
1167-58-4Downstream Products
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5α-Hydroxy-11-methoxy-1-methyl-9,10-(methylenebisoxy)lycorenan-7-one
