1167-64-2

Basic information

• Product Name: {9-phenyl-1H,2H,3H-cyclopenta[b]naphthalen-4-yl}benzene
• Synonyms: {9-phenyl-1H,2H,3H-cyclopenta[b]naphthalen-4-yl}benzene
• CAS NO: 1167-64-2
• Molecular Weight: 320.434
• Mol File: 1167-64-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: {9-phenyl-1H,2H,3H-cyclopenta[b]naphthalen-4-yl}benzene(CAS DataBase Reference)
• NIST Chemistry Reference: {9-phenyl-1H,2H,3H-cyclopenta[b]naphthalen-4-yl}benzene(1167-64-2)
• EPA Substance Registry System: {9-phenyl-1H,2H,3H-cyclopenta[b]naphthalen-4-yl}benzene(1167-64-2)

Safety Data

• Hazardous Substances Data: 1167-64-2(Hazardous Substances Data)

Upstream product

• 1169-09-1 1,4-Epoxi-1,4-diphenyl-1,4-dihydro-2,3-cyclopenteno-naphthalin 
• 1172-77-6 2,3-Dibrom-1,4-epoxy-1,4-diphenyl-2,3-cyclopentano-1,2,3,4-tetrahydro-naphthalin 
• 615-42-9 1,2-Diiodobenzene 
• 49769-17-7 1,7-diphenylhepta-1,6-diyne 
• 65-85-0 benzoic acid 
• 71-43-2 benzene 

Relevant articles and documents

Dienylation of Unfunctionalized Arenes with 1,6-Diynes via Rhodium-Catalyzed Directing-Group-Free C-H Bond Activation

It has been established that the dienylation of unfunctionalized arenes with 1,6-diynes, possessing aryl groups at the diyne termini, proceeds to give the corresponding dienylated arenes in the presence of a catalytic amount of an electron-deficient cyclopentadienyl rhodium(III) complex, [Cp ERhCl 2] 2, and a stoichiometric amount of silver carbonate. Experimental and theoretical mechanistic studies revealed that a Cp ERh(I) complex generated in situ might catalyze the present dienylation- reaction.

O-Dihaloarenes as aryne precursors for nickel-catalyzed [2 + 2 + 2] cycloaddition with alkynes and nitriles

o-Dihaloarenes acting as aryne precursors react with acetylenes and nitriles catalyzed by the NiBr2(dppe)/dppe/Zn system to give substituted naphthalene, phenanthridine or triphenylene derivatives depending on the reaction conditions in moderat